|ACUTE HAZARDS / SYMPTOMS||PREVENTION||FIRST AID / FIRE FIGHTING|
|FIRE||Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire.||NO open flames, NO sparks and NO smoking.||Use powder, AFFF, foam, carbon dioxide.|
|EXPLOSION||Vapour/air mixtures are explosive. Risk of fire and explosion on contact with incompatible substances. See Chemical Dangers.||Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling.||In case of fire: keep drums, etc., cool by spraying with water.|
|EXPOSURE||STRICT HYGIENE!||IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Cough. Sore throat. Headache. Dizziness. Weakness. Laboured breathing. Vomiting. Unconciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.|
|Skin||Redness. Burning sensation. Pain.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain. Blurred vision.||Wear safety goggles or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Burning sensation. Vomiting.||Do not eat, drink, or smoke during work.||Rinse mouth. Give a slurry of activated charcoal in water to drink. Give one or two glasses of water to drink. Refer for medical attention .|
|PACKAGING & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.||
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
Symbol: F, Xn, N; R: 11-20/21/22-36/37/38-40-48/20-68-50; S: (2)-16-25-26-36/37-46-61; Note: D
UN Hazard Class: 3; UN Subsidiary Risks: 6.1; UN Pack Group: I
|EMERGENCY RESPONSE||SAFE STORAGE|
Transport Emergency Card: TEC (R)-30S1100.
NFPA Code: H3; F3; R1.
|Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Dry.|
Physical State; Appearance
COLOURLESS LIQUID WITH PUNGENT ODOUR.
Occupational exposure limits
Routes of exposure
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.
Effects of short-term exposure
Effects of long-term or repeated exposure
|PHYSICAL PROPERTIES||ENVIRONMENTAL DATA|
Boiling point: 45°C
Melting point: -135°C
Relative density (water = 1): 0.94
Solubility in water, g/100ml at 20°C: 0.36
Vapour pressure, kPa at 20°C: 39.3
Relative vapour density (air = 1): 2.6
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.6
Flash point: -32°C c.c.
Auto-ignition temperature: 390°C
Explosive limits, vol% in air: 2.9-11.2
Octanol/water partition coefficient as log Pow: 2.1
|The substance is harmful to aquatic organisms.|
Depending on the degree of exposure, periodic medical examination is suggested.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.
See Also: Toxicological Abbreviations Allyl Chloride (IARC Summary & Evaluation, Volume 36, 1985) Allyl Chloride (IARC Summary & Evaluation, Volume 71, 1999)