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PENTACHLOROPHENOLICSC: 0069
August 2003
CAS #: 87-86-5
UN #: 3155
EC Number: 201-778-6

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Not combustible. Liquid formulations containing organic solvents may be flammable.        In case of fire in the surroundings, use appropriate extinguishing media.   

 PREVENT DISPERSION OF DUST! STRICT HYGIENE! AVOID EXPOSURE OF (PREGNANT) WOMEN! AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! 
  SYMPTOMS PREVENTION FIRST AID
Inhalation Cough. Dizziness. Drowsiness. Headache. Fever. Laboured breathing. Sore throat.  Use local exhaust or breathing protection.  Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. 
Skin MAY BE ABSORBED! Redness. Blisters. Further see Inhalation.  Protective gloves. Protective clothing.  Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention . Wear protective gloves when administering first aid. 
Eyes Redness. Pain.  Wear safety goggles, face shield or eye protection in combination with breathing protection.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Abdominal cramps. Diarrhoea. Nausea. Unconsciousness. Vomiting. Weakness. Further see Inhalation.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Give a slurry of activated charcoal in water to drink. Give one or two glasses of water to drink. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: chemical protection suit and filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. 

According to UN GHS Criteria

 

Transportation
UN Classification
UN Hazard Class: 6.1; UN Pack Group: II 

STORAGE
Provision to contain effluent from fire extinguishing. Separated from strong oxidants and food and feedstuffs. Keep in a well-ventilated room. 
PACKAGING
Do not transport with food and feedstuffs.
Severe marine pollutant. 
PENTACHLOROPHENOL ICSC: 0069
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
WHITE CRYSTALS OR SOLID IN VARIOUS FORMS WITH CHARACTERISTIC ODOUR. 

Physical dangers
 

Chemical dangers
Decomposes above 200°C . This produces toxic and corrosive fumes including dioxins. Reacts violently with strong oxidants. 

Formula: C6Cl5OH
Molecular mass: 266.4
Decomposes at 309°C
Melting point: 191°C
Density: 1.98 g/cm³
Solubility in water, g/100ml at 20°C: 0.001
Vapour pressure, Pa at 20°C: 0.02
Relative vapour density (air = 1): 9.2
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Octanol/water partition coefficient as log Pow: 5.01  


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation, through the skin and by ingestion. 

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the cardiovascular system. This may result in cardiac disorders and heart failure. 

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed. 

Effects of long-term or repeated exposure
The substance may have effects on the central nervous system, kidneys, liver, lungs, immune system and thyroid. This substance is possibly carcinogenic to humans. Animal tests show that this substance possibly causes toxicity to human reproduction or development. 


OCCUPATIONAL EXPOSURE LIMITS
TLV: 0.5 mg/m3, as TWA; 1 mg/m3 as STEL; (skin); A3 (confirmed animal carcinogen with unknown relevance to humans); BEI issued.
MAK: skin absorption (H); carcinogen category: 2 

ENVIRONMENT
The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal. 

NOTES
The commercial product may contain very toxic impurities (dioxins).
The odour warning when the exposure limit value is exceeded is insufficient. 

ADDITIONAL INFORMATION
  EC Classification
Symbol: T+, N; R: 24/25-26-36/37/38-40-50/53; S: (1/2)-22-36/37-45-52-60-61 

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    See Also:
       Toxicological Abbreviations
       Pentachlorophenol (EHC 71, 1987)
       Pentachlorophenol (HSG 19, 1989)
       Pentachlorophenol (PIM 405)
       Pentachlorophenol (IARC Summary & Evaluation, Volume 53, 1991)