|CAS #: 74-86-2||Ethine
| UN #: 1001
| EINECS #: 200-816-9
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Extremely flammable. Gas/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Use non-sparking handtools. Flame arrester to prevent flash-back from burner to cylinder.||Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water.|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Dizziness. Lethargy. Headache. Suffocation.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.|
|Eyes||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Do not eat, drink, or smoke during work.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Ventilation.||
According to UN GHS Criteria
|Fireproof. See Chemical Dangers. Cool.|
|Special insulated cylinder.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
|Piping material for this gas must not contain over 63% of copper.
Check oxygen content before entering area.
After use for welding, turn valve off; regularly check tubing, etc., and test for leaks with soap and water.
The technical product may contain impurities which alter the health effects; for further information see ICSC0694 Phosphine.
Symbol: F+; R: 5-6-12; S: (2)-9-16-33
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations