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PHOSPHORUS OXYCHLORIDEICSC: 0190
June 1997
CAS #: 10025-87-3Phosphoryl chloride
Trichlorophosphorus oxide
Trichlorophosphine oxide
UN #: 1810
EINECS #: 233-046-7

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.    NO contact with water.    In case of fire in the surroundings, use appropriate extinguishing media. NO hydrous agents. NO water.  In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water. 

 AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! 
  SYMPTOMS ACUTE HAZARDS FIRST AID
Inhalation Sore throat. Cough. Burning sensation. Dizziness. Laboured breathing. Nausea. Headache. Unconsciousness. Vomiting. Weakness. Shortness of breath. Symptoms may be delayed. See Notes.  Use ventilation, local exhaust or breathing protection.  Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. 
Skin Pain. Redness. Blisters. Skin burns.  Protective gloves. Protective clothing.  Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . 
Eyes Pain. Redness. Severe deep burns. Loss of vision.  Wear face shield or eye protection in combination with breathing protection.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Burning sensation. Abdominal pain. Shock or collapse. Further see Inhalation.  Do not eat, drink, or smoke during work.  Rinse mouth. Do NOT induce vomiting. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable dry containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations. 

According to UN GHS Criteria

 

Transportation
UN Classification
UN Hazard Class: 8; UN Pack Group: II 

STORAGE
See Chemical Dangers. Cool. Dry. Well closed. Keep in a well-ventilated room. 
PACKAGING
Airtight.
Unbreakable packaging.
Put breakable packaging into closed unbreakable container. 
PHOSPHORUS OXYCHLORIDE ICSC: 0190
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
BROWN FUMING LIQUID WITH PUNGENT ODOUR. 

Physical dangers
The vapour is heavier than air. 

Chemical dangers
Decomposes on heating. This produces toxic and corrosive fumes including hydrogen chloride and phosphorus oxides. Reacts violently with water. This produces heat and decomposition products including hydrochloric acid and phosphoric acid. This generates fire and explosion hazard. Reacts violently with alcohols, phenols, amines and many other materials. 

Formula: POCl3
Molecular mass: 153.35
Boiling point: 105.8°C
Melting point: 1.25°C
Relative density (water = 1): 1.645
Solubility in water: reaction
Vapour pressure, kPa at 27.3°C: 5.3
Relative vapour density (air = 1): 5.3  


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour and by ingestion. 

Effects of short-term exposure
The substance is corrosive to the eyes, skin and respiratory tract. Inhalation of the vapour may cause lung oedema. See Notes. Exposure at high levels could cause death. The effects may be delayed. Medical observation is indicated. 

Inhalation risk
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C. 

Effects of long-term or repeated exposure
 


Occupational exposure limits
TLV: 0.1 ppm as TWA.
MAK: 0.13 mg/m3, 0.02 ppm; peak limitation category: I(1); pregnancy risk group: C 

ENVIRONMENT
 

NOTES
Reacts violently with fire extinguishing agents such as water.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation is therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered. 

ADDITIONAL INFORMATION
  EC Classification
Symbol: T+, C; R: 14-22-26-29-35-48/23; S: (1/2)-7/8-26-36/37/39-45 

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    See Also:
       Toxicological Abbreviations