ICSC 0201 - TRI-ALLATE

TRI-ALLATE	ICSC: 0201 (April 2005)
S-(2,3,3-Trichloroallyl) diisopropylthiocarbamate S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate

CAS #: 2303-17-5

EC Number: 218-962-7

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	In case of fire in the surroundings, use appropriate extinguishing media.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation		Avoid inhalation of dust and mist.	Fresh air, rest.
Skin	Redness.	Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes	Redness.	Wear safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion		Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification
STORAGE
Store in an area without drain or sewer access. Separated from food and feedstuffs.
PACKAGING
Do not transport with food and feedstuffs.

TRI-ALLATE

ICSC: 0201

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance CLEAR LIQUID OR COLOURLESS CRYSTALS. Physical dangers Chemical dangers Decomposes above 200°C . This produces toxic and corrosive gases including hydrogen chloride, nitrogen oxides and sulfur oxides. Attacks many metals.	Formula: C₁₀H₁₆Cl₃NOS / ((CH₃)₂CH)₂NCOSCH₂CCl=CCl₂ Molecular mass: 304.7 Boiling point at 0.04kPa: 117°C Melting point: 29-30°C Relative density (water = 1): 1.27 Solubility in water, g/100ml at 25°C: 0.0002 Vapour pressure, Pa at 25°C: 0.016 Relative vapour density (air = 1): 10.5 Flash point: 90°C c.c. Octanol/water partition coefficient as log Pow: 3.98 (calculated)

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
CLEAR LIQUID OR COLOURLESS CRYSTALS.

Physical dangers

Chemical dangers
Decomposes above 200°C . This produces toxic and corrosive gases including hydrogen chloride, nitrogen oxides and sulfur oxides. Attacks many metals.

Formula: C₁₀H₁₆Cl₃NOS / ((CH₃)₂CH)₂NCOSCH₂CCl=CCl₂
Molecular mass: 304.7
Boiling point at 0.04kPa: 117°C
Melting point: 29-30°C
Relative density (water = 1): 1.27
Solubility in water, g/100ml at 25°C: 0.0002
Vapour pressure, Pa at 25°C: 0.016
Relative vapour density (air = 1): 10.5
Flash point: 90°C c.c.
Octanol/water partition coefficient as log Pow: 3.98 (calculated)

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation and by ingestion. Effects of short-term exposure The substance is irritating to the eyes and skin.	Inhalation risk A harmful concentration of airborne particles can be reached quickly on spraying or when dispersed, especially if powdered. Effects of long-term or repeated exposure

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes and skin.

Inhalation risk
A harmful concentration of airborne particles can be reached quickly on spraying or when dispersed, especially if powdered.

Effects of long-term or repeated exposure

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur in aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.

NOTES
Technical Tri-allate is an oily amber liquid. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties.

ADDITIONAL INFORMATION

EC Classification
Symbol: Xn, N; R: 22-43-48/22-50/53; S: (2)-24-37-60-61

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    See Also:
       Toxicological Abbreviations
       Tri-allate (HSG 89, 1994)