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TRI-ALLATEICSC: 0201
April 2005
CAS #: 2303-17-5S-(2,3,3-Trichloroallyl) diisopropylthiocarbamate
S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate
EINECS #: 218-962-7

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.    NO open flames.    In case of fire in the surroundings, use appropriate extinguishing media.   

   
  SYMPTOMS ACUTE HAZARDS FIRST AID
Inhalation   Avoid inhalation of dust and mist.  Fresh air, rest. 
Skin Redness.  Protective gloves.  Remove contaminated clothes. Rinse skin with plenty of water or shower. 
Eyes Redness.  Wear safety spectacles.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion   Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. 

According to UN GHS Criteria

 

Transportation
UN Classification
 

STORAGE
Store in an area without drain or sewer access. Separated from food and feedstuffs. 
PACKAGING
Do not transport with food and feedstuffs. 
TRI-ALLATE ICSC: 0201
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
CLEAR LIQUID OR COLOURLESS CRYSTALS. 

Physical dangers
 

Chemical dangers
Decomposes above 200°C . This produces toxic and corrosive gases including hydrogen chloride, nitrogen oxides and sulfur oxides. Attacks many metals. 

Formula: C10H16Cl3NOS / ((CH3)2CH)2NCOSCH2CCl=CCl2
Molecular mass: 304.7
Boiling point at 0.04kPa: 117°C
Melting point: 29-30°C
Relative density (water = 1): 1.27
Solubility in water, g/100ml at 25°C: 0.0002
Vapour pressure, Pa at 25°C: 0.016
Relative vapour density (air = 1): 10.5
Flash point: 90°C c.c.
Octanol/water partition coefficient as log Pow: 3.98 (calculated) 


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion. 

Effects of short-term exposure
The substance is irritating to the eyes and skin. 

Inhalation risk
A harmful concentration of airborne particles can be reached quickly on spraying or when dispersed, especially if powdered. 

Effects of long-term or repeated exposure
 


Occupational exposure limits
 

ENVIRONMENT
The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur in aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal. 

NOTES
Technical Tri-allate is an oily amber liquid.
If the substance is formulated with solvents also consult the ICSCs of these materials.
Carrier solvents used in commercial formulations may change physical and toxicological properties. 

ADDITIONAL INFORMATION
  EC Classification
Symbol: Xn, N; R: 22-43-48/22-50/53; S: (2)-24-37-60-61 

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    See Also:
       Toxicological Abbreviations
       Tri-allate (HSG 89, 1994)