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ARSENIC TRICHLORIDEICSC: 0221
October 2000
CAS #: 7784-34-1Arsenic III chloride
Arsenous chloride
UN #: 1560
EINECS #: 232-059-5

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.  Risk of fire and explosion on contact with water or metals.  NO contact with water or metals.    In case of fire in the surroundings, use appropriate extinguishing media.   

 AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! 
  SYMPTOMS ACUTE HAZARDS FIRST AID
Inhalation Headache. Cough. Laboured breathing. Sore throat. See Ingestion.  Use closed system or ventilation.  Fresh air, rest. Half-upright position. Refer for medical attention. 
Skin Redness. Pain.  Protective gloves. Protective clothing.  Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . 
Eyes Redness. Pain.  Wear safety spectacles, face shield or eye protection in combination with breathing protection.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Abdominal pain. Diarrhoea. Nausea. Vomiting. Shock or collapse.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Do NOT induce vomiting. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable plastic containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations. 

According to UN GHS Criteria

 

Transportation
UN Classification
UN Hazard Class: 6.1; UN Pack Group: I 

STORAGE
Separated from food and feedstuffs. Cool. Dry. Ventilation along the floor. 
PACKAGING
Unbreakable packaging.
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
Marine pollutant. 
ARSENIC TRICHLORIDE ICSC: 0221
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS OILY FUMING LIQUID WITH PUNGENT ODOUR. 

Physical dangers
 

Chemical dangers
Decomposes on heating. This produces toxic fumes of hydrogen chloride (see ICSC 0163) and arsenic oxides. Reacts violently with water and moist air. This produces hydrogen chloride (see ICSC 0163). Attacks many metals. This produces flammable/explosive gas (hydrogen - see ICSC 0001). 

Formula: AsCl3
Molecular mass: 181.2
Boiling point: 130.2°C
Melting point: -16°C
Density: 2.1 g/cm³
Solubility in water: reaction
Vapour pressure, kPa at 20°C: 1.17
Relative vapour density (air = 1): 6.3
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.06 


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour and by ingestion. 

Effects of short-term exposure
The substance is severely irritating to the eyes, skin and respiratory tract. The substance may cause effects on the gastrointestinal tract, cardiovascular system and central nervous system. This may result in severe gastroenteritis, loss of fluids and electrolytes, cardiac disorders, shock and convulsions. Exposure above the OEL could cause death. The effects may be delayed. Medical observation is indicated. 

Inhalation risk
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C. 

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the mucous membranes, skin, peripheral nervous system, liver and bone marrow. This may result in pigmentation disorders, hyperkeratosis, perforation of the nasal septum, neuropathy, liver impairment and anaemia. This substance is carcinogenic to humans. Animal tests show that this substance possibly causes malformations in human babies. 


Occupational exposure limits
TLV: 0.01 mg/m3, - ppm, as TWA; A1 (confirmed human carcinogen); BEI issued.
MAK: skin absorption (H); carcinogen category: 1; germ cell mutagen group: 3A 

ENVIRONMENT
This substance may be hazardous to the environment. Special attention should be given to soil organisms and aquatic organisms. It is strongly advised not to let the chemical enter into the environment. 

NOTES
The apparent melting point caused by loss of crystal water is given.
Depending on the degree of exposure, periodic medical examination is suggested.
Do NOT take working clothes home. 

ADDITIONAL INFORMATION
  EC Classification
Symbol: T, N; R: 23/25-50/53; S: (1/2)-20/21-28-45-60-61; Note: A 

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       Toxicological Abbreviations