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BUTYL ACRYLATEICSC: 0400
November 2003
CAS #: 141-32-2Acrylic acid n-butyl ester
2-Propenoic acid, butyl ester
Butyl 2-propenoate
UN #: 2348
EINECS #: 205-480-7

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Flammable.  Above 36°C explosive vapour/air mixtures may be formed.  NO open flames, NO sparks and NO smoking. NO contact with strong oxidizing agents.  Above 36°C use a closed system, ventilation and explosion-proof electrical equipment. NO contact with strong oxidizing agents.  Use powder, AFFF, foam, carbon dioxide.  In case of fire: keep drums, etc., cool by spraying with water. 

 PREVENT GENERATION OF MISTS! AVOID ALL CONTACT!  
  SYMPTOMS ACUTE HAZARDS FIRST AID
Inhalation Burning sensation. Cough. Shortness of breath. Sore throat.  Use ventilation, local exhaust or breathing protection.  Fresh air, rest. Refer for medical attention. 
Skin Redness. Pain.  Protective gloves. Protective clothing.  Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . 
Eyes Redness. Pain.  Wear safety goggles or eye protection in combination with breathing protection.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Abdominal pain. Nausea. Vomiting. Diarrhoea.  Do not eat, drink, or smoke during work.  Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: chemical protection suit and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Remove all ignition sources. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. 

According to UN GHS Criteria

 

Transportation
UN Classification
UN Hazard Class: 3; UN Pack Group: III 

STORAGE
Fireproof. Cool. Keep in the dark. Separated from strong oxidants. Store only if stabilized. 
PACKAGING
 
BUTYL ACRYLATE ICSC: 0400
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. 

Physical dangers
Vapours are uninhibited and may polymerize, causing blockage of vents. 

Chemical dangers
The substance may spontaneously polymerize due to warming, under the influence of light and on contact with peroxides. Reacts violently with strong oxidants. This generates fire and explosion hazard. 

Formula: CH2=CHCOOC4H9 / C7H12O2
Molecular mass: 128.2
Boiling point: 145-149°C
Melting point: -64°C
Relative density (water = 1): 0.90
Solubility in water, g/100ml: 0.14
Vapour pressure, kPa at 20°C: 0.43
Relative vapour density (air = 1): 4.42
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01
Flash point: 36°C c.c.
Auto-ignition temperature: 267°C
Explosive limits, vol% in air: 1.3-9.9
Octanol/water partition coefficient as log Pow: 2.38  


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation and through the skin. 

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. 

Inhalation risk
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C. 

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization. 


Occupational exposure limits
TLV: 2 ppm as TWA; A4 (not classifiable as a human carcinogen); (SEN).
MAK: 11 mg/m3, 2 ppm; peak limitation category: I(2); skin absorption (H); sensitization of skin (SH); pregnancy risk group: C.
EU-OEL: 11 mg/m3, 2 ppm as TWA; 53 mg/m3, 10 ppm as STEL 

ENVIRONMENT
The substance is toxic to aquatic organisms. 

NOTES
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
Hydroquinone and hydroquinone ethyl ether are the commonly used stabilizers.
Do NOT take working clothes home. 

ADDITIONAL INFORMATION
  EC Classification
Symbol: Xi; R: 10-36/37/38-43; S: (2)-9; Note: D 

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    See Also:
       Toxicological Abbreviations