|CAS #: 122-14-5||O,O-Dimethyl O-4-nitro-m-tolyl phosphorothioate
O,O-Dimethyl O-(3-methyl-4-nitrophenyl) phosphorothioate
O,O-Dimethyl O-4-nitro-m-tolyl thiophosphate
| UN #: 3018
| EINECS #: 204-524-2
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.||NO open flames.||Use water spray, powder, foam, carbon dioxide. See Notes.|
|PREVENT GENERATION OF MISTS! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR!|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Cough. Headache. Pupillary constriction, muscle cramp, excessive salivation. Nausea. Dizziness. Laboured breathing. Convulsions. Sweating. Unconsciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Redness. Pain. Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal cramps. Confusion. Diarrhoea. Shortness of breath. Vomiting. Further see Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. Personal protection: chemical protection suit including self-contained breathing apparatus.||
According to UN GHS Criteria
|Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in a well-ventilated room.|
|Do not transport with food and feedstuffs.
Severe marine pollutant.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
|The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to crustacea and bees. Bioaccumulation of this chemical may occur in fish.|
|Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
Symbol: Xn, N; R: 22-50/53; S: (2)-60-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations Fenitrothion (EHC 133, 1992) Fenitrothion (HSG 65, 1991) Fenitrothion (FAO/PL:1969/M/17/1) Fenitrothion (WHO Pesticide Residues Series 4) Fenitrothion (Pesticide residues in food: 1976 evaluations) Fenitrothion (Pesticide residues in food: 1977 evaluations) Fenitrothion (Pesticide residues in food: 1979 evaluations) Fenitrothion (Pesticide residues in food: 1982 evaluations) Fenitrothion (Pesticide residues in food: 1983 evaluations) Fenitrothion (Pesticide residues in food: 1984 evaluations) Fenitrothion (Pesticide residues in food: 1986 evaluations Part II Toxicology) Fenitrothion (Pesticide residues in food: 1988 evaluations Part II Toxicology) Fenitrothion (JMPR Evaluations 2000 Part II Toxicological)