| ||||||||||||||
| ||||||||||||||
|
||||||||||||||
| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
|
|
In case of fire in the surroundings: use appropriate extinguishing media.
|
| EXPLOSION |
|
|
|
| EXPOSURE |
|
STRICT HYGIENE!
|
|
| Inhalation |
|
Ventilation (not if powder), local exhaust, or breathing protection.
|
Refer for medical attention.
|
| Skin |
|
Protective gloves. Protective clothing.
|
Remove contaminated clothes. Rinse skin with plenty of water or shower.
|
| Eyes |
|
Face shield or eye protection in combination with breathing protection if powder.
|
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
|
| Ingestion |
|
Do not eat, drink, or smoke during work. Wash hands before eating.
|
Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
|
| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
|
Do NOT wash away into sewer. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: P3 filter respirator for toxic particles.
|
Do not transport with food and feedstuffs. Severe marine pollutant. EU Classification Symbol: Xn, N R: 48/22-63-51/53 S: (2-)-13-36/37-61 UN Classification UN Hazard Class: 6.1 UN Pack Group: III | |||||||
| EMERGENCY RESPONSE | STORAGE | |||||||
|
Transport Emergency Card: TEC (R)-61GT7-III
|
Separated from food and feedstuffs, incompatible materials. See Chemical Dangers. Keep in the dark. Keep in a well-ventilated room.
| |||||||
| ||||||||
| |||
| IMPORTANT DATA | |||
|
PHYSICAL STATE; APPEARANCE: ODOURLESS, COLOURLESS CRYSTALS. CHEMICAL DANGERS: The substance decomposes on heating producing toxic fumes 0f nitrogen oxides. The substance is a weak base. Reacts with strong acids, strong oxidants, acid chlorides and acid anhydrides. Attacks iron, copper and aluminium. OCCUPATIONAL EXPOSURE LIMITS: TLV: 0.2 mg/m³ as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans); (ACGIH 2004). MAK: (Inhalable fraction) 0.2 mg/m³; Peak limitation category: II(8); Carcinogen category: 3B; Pregnancy risk group: C; (DFG 2005). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the thyroid. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the thyroid, resulting in goitrogenic effects. | ||
| PHYSICAL PROPERTIES | |||
|
Melting point: 159°C Solubility in water: good |
Octanol/water partition coefficient as log Pow: -0.65 | ||
| ENVIRONMENTAL DATA | |||
|
This substance may be hazardous in the environment; special attention should be given to plants.
| |||
| NOTES | |||
|
Temperature of decomposition unknown in literature. Depending on the degree of exposure, periodic medical examination is suggested. Card has been partly updated in October 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.
| |||
| ADDITIONAL INFORMATION | |||
|
| |||
| |||
| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations
Amitrole (EHC 158, 1994)
Amitrole (HSG 85, 1994)
Amitrole (PDS)
Amitrole (WHO Pesticide Residues Series 4)
Amitrole (Pesticide residues in food: 1977 evaluations)
Amitrole (Pesticide residues in food: 1993 evaluations Part II Toxicology)
Amitrole (Pesticide residues in food: 1997 evaluations Part II Toxicological & Environmental)
Amitrole (IARC Summary & Evaluation, Supplement7, 1987)
Amitrole (IARC Summary & Evaluation, Volume 7, 1974)
Amitrole (IARC Summary & Evaluation, Volume 41, 1986)
Amitrole (IARC Summary & Evaluation, Volume 79, 2001)