|CAS #: 8018-01-7||Manganese ethylenebis(dithiocarbamate)(polymeric)complex with zinc salt
| UN #: 2210
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Finely dispersed particles form explosive mixtures in air.||NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust.||Use water spray, powder, foam, carbon dioxide.|
|PREVENT DISPERSION OF DUST! AVOID ALL CONTACT!|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Cough. Sore throat.||Use local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||Redness.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap.|
|Eyes||Redness. Pain.||Wear safety goggles or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Diarrhoea. Nausea. Vomiting.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!).|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into sealable containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT wash away into sewer.||
According to UN GHS Criteria
|Provision to contain effluent from fire extinguishing. Separated from acids and food and feedstuffs. Dry. Keep in a well-ventilated room.|
Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C4H6N2S4Mn . C4H6N2S4Zn
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
|The substance is toxic to aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.|
|Maneb, a related substance, may cause also other effects after long-term exposure.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
See ICSC1148, 2-Mercaptoimidazoline, a contaminant and breakdown product, ICSC0173 Maneb and ICSC0350 Zineb.
Symbol: Xi; R: 37-43; S: (2)-8-24/25-46
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations Mancozeb (FAO/PL:1967/M/11/1) Mancozeb (AGP:1970/M/12/1) Mancozeb (WHO Pesticide Residues Series 4) Mancozeb (Pesticide residues in food: 1993 evaluations Part II Toxicology)