|ACUTE HAZARDS / SYMPTOMS||PREVENTION||FIRST AID / FIRE FIGHTING|
|FIRE||Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.||NO open flames.||Use powder, water spray, foam, carbon dioxide.|
|EXPOSURE||STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!||IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Pupillary constriction, muscle cramp, excessive salivation. Blurred vision. Sweating. Nausea. Vomiting. Diarrhoea. Abdominal cramps. Dizziness. Convulsions. Unconciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer immediately for medical attention. See Notes.|
|Skin||MAY BE ABSORBED! Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Wear protective gloves when administering first aid. Refer immediately for medical attention.|
|Eyes||Blurred vision.||Wear face shield or eye protection in combination with breathing protection.||Rinse with plenty of water (remove contact lenses if easily possible).|
|Ingestion||See Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer immediately for medical attention. See Notes.|
|PACKAGING & LABELLING|
|Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
Do not transport with food and feedstuffs.
Severe marine pollutant.
Symbol: T+, N; R: 27/28-50/53; S: (1/2)-23-28-36/37-45-60-61
UN Hazard Class: 6.1; UN Pack Group: I
Fatal if swallowed
Fatal in contact with skin
Fatal if inhaled vapour
Causes damage to nervous system
Very toxic to aquatic life
|EMERGENCY RESPONSE||SAFE STORAGE|
|Transport Emergency Card: TEC (R)-61GT6-I.||Separated from food and feedstuffs and strong oxidants. Keep in a well-ventilated room. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.|
Physical State; Appearance
Occupational exposure limits
Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.
Effects of short-term exposure
Effects of long-term or repeated exposure
|PHYSICAL PROPERTIES||ENVIRONMENTAL DATA|
Decomposes at 300°C
Melting point: 6.9°C (trans), 21°C (cis)
Relative density (water = 1): 1.25
Solubility in water: miscible
Vapour pressure, Pa at 21°C: 0.38
Flash point: 175°C o.c.
Octanol/water partition coefficient as log Pow: 1.2
|The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to birds and bees. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.|
Depending on the degree of exposure, periodic medical examination is suggested.
Consult national legislation.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
See Also: Toxicological Abbreviations