|CAS #: 99-99-0||4-Nitrotoluene
| UN #: 1664
| EINECS #: 202-808-0
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Risk of fire and explosion on contact with acids or oxidizing agents.||NO open flames. NO contact with oxidizing agents.||Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|PREVENT DISPERSION OF DUST! STRICT HYGIENE!|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Headache. Blue lips, fingernails and skin. Dizziness. Laboured breathing.||Use local exhaust or breathing protection.||Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Further see Inhalation.||Protective gloves. Protective clothing.||Rinse and then wash skin with water and soap. Refer for medical attention . Wear protective gloves when administering first aid.|
|Eyes||Redness. Pain.||Wear safety goggles, face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Further see Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Separated from food and feedstuffs. See Chemical Dangers. Well closed.|
|Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C7H7NO2 / C6H4(CH3)NO2
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
TLV: 2 ppm as TWA; (skin); BEI issued.
MAK: skin absorption (H); carcinogen category: 3B
|The substance is toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment.|
|Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Depending on the degree of exposure, periodic medical examination is suggested.
Symbol: T, N; R: 23/24/25-33-51/53; S: (1/2)-28-37-45-61; Note: C
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations