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SELENIUM TRIOXIDEICSC: 0949
March 2000
CAS #: 13768-86-0Selenic anhydride
UN #: 3283
EINECS #: 237-385-1

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Not combustible but enhances combustion of other substances. Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire.    NO contact with combustible substances.    In case of fire in the surroundings, use appropriate extinguishing media.   

 PREVENT DISPERSION OF DUST! STRICT HYGIENE!  
  SYMPTOMS ACUTE HAZARDS FIRST AID
Inhalation Burning sensation. Cough. Laboured breathing. Sore throat. Shortness of breath. Symptoms may be delayed. See Notes.  Use ventilation, local exhaust or breathing protection.  Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. 
Skin Redness. Pain. Blisters. Skin burns.  Protective gloves. Protective clothing.  First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer for medical attention . 
Eyes Redness. Pain. Severe deep burns.  Wear face shield or eye protection in combination with breathing protection.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Sore throat. Nausea. Abdominal pain. Burning sensation. Diarrhoea. Vomiting. Shock or collapse.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Do NOT induce vomiting. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Evacuate danger area! Consult an expert! Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations. Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT absorb in saw-dust or other combustible absorbents. Do NOT let this chemical enter the environment. 

According to UN GHS Criteria

 

Transportation
UN Classification
UN Hazard Class: 6.1; UN Pack Group: II 

STORAGE
Separated from combustible substances and food and feedstuffs. Dry. Keep in a well-ventilated room. 
PACKAGING
Do not transport with food and feedstuffs. 
SELENIUM TRIOXIDE ICSC: 0949
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
YELLOWISH WHITE HYGROSCOPIC CRYSTALLINE POWDER. 

Physical dangers
 

Chemical dangers
Decomposes on heating. This produces toxic fumes. The solution in water is a strong acid. It reacts violently with bases and is corrosive. The substance is a strong oxidant. It reacts with combustible and reducing materials. 

Formula: SeO3
Molecular mass: 126.9
Decomposes at 180°C
Melting point: 118°C
Density: 3.6 g/cm³
Solubility in water: very good 


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. 

Effects of short-term exposure
The substance is corrosive to the eyes, skin and respiratory tract. Inhalation may cause lung oedema. See Notes. The substance may cause effects on the eyes. This may result in allergic-type reaction of the eyelids (rose eye). Medical observation is indicated. 

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly , especially if powdered. 

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the respiratory tract, central nervous system, gastrointestinal tract and liver. This may result in nasal irritation, persistent garlic odour, stomach pain, nervousness and liver impairment. 


Occupational exposure limits
TLV: 0.2 mg/m3, ppm, as TWA.
MAK: (as Se, inhalable fraction): 0.02 mg/m3; peak limitation category: II(8); skin absorption (H); carcinogen category: 3B; pregnancy risk group: C 

ENVIRONMENT
The substance is harmful to aquatic organisms. 

NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation is therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered. 

ADDITIONAL INFORMATION
  EC Classification
Symbol: T, N; R: 23/25-33-50/53; S: (1/2)-20/21-28-45-60-61; Note: A 

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    See Also:
       Toxicological Abbreviations