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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
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In case of fire in the surroundings: use appropriate extinguishing media.
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| EXPLOSION |
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| EXPOSURE |
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STRICT HYGIENE!
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| Inhalation |
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Local exhaust or breathing protection.
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Fresh air, rest. Refer for medical attention.
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| Skin |
MAY BE ABSORBED! Chloracne.
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Protective gloves. Protective clothing.
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Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
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| Eyes |
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Safety goggles face shield or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
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Do not eat, drink, or smoke during work. Wash hands before eating.
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Rinse mouth. Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Sweep spilled substance into containers. Carefully collect remainder, then remove to safe place. Personal protection: P3 filter respirator for toxic particles.
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EU Classification UN Classification | |||||||
| EMERGENCY RESPONSE | SAFE STORAGE | |||||||
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: WAXY, YELLOW SOLID IN VARIOUS FORMS, WITH CHARACTERISTIC ODOUR. CHEMICAL DANGERS: The substance decomposes on heating producing toxic fumes including hydrogen chloride. OCCUPATIONAL EXPOSURE LIMITS: TLV: 0.1 mg/m³ as TWA, 0.3 mg/m³ as STEL; (skin); (ACGIH 2004). MAK: IIb (not established but data is available); skin absorption (H); (DFG 2004). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the liver, resulting in tissue lesions. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the liver. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 440°C Melting point: 192°C Relative density (water = 1): 2.0 Solubility in water: none Vapour pressure, kPa at 20°C: <0.13 |
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01 Octanol/water partition coefficient as log Pow: 5.88-6.2 | ||
| ENVIRONMENTAL DATA | |||
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Bioaccumulation of this chemical may occur along the food chain, for example in fish. It is strongly advised not to let the chemical enter into the environment because it persists in the environment.
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| NOTES | |||
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Card has been partly updated in April 2005. See section Occupational Exposure Limits.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2004 | |||
See Also:
Toxicological Abbreviations