
| ||||||||||||||
| ||||||||||||||
|
||||||||||||||
| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Flammable.
|
NO open flames, NO sparks, and NO smoking.
|
Powder, alcohol-resistant foam, water spray, carbon dioxide.
|
| EXPLOSION |
Above 60°C explosive vapour/air mixtures may be formed.
|
Above 60°C use a closed system, ventilation, and explosion-proof electrical equipment.
|
In case of fire: keep cylinder cool by spraying with water.
|
| EXPOSURE |
|
|
|
| Inhalation |
Cough. Sore throat.
|
Ventilation, local exhaust, or breathing protection.
|
Fresh air, rest.
|
| Skin |
Redness.
|
Protective gloves.
|
Remove contaminated clothes. Rinse skin with plenty of water or shower.
|
| Eyes |
Redness. Pain.
|
Safety goggles.
|
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
|
| Ingestion |
|
Do not eat, drink, or smoke during work.
|
Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention.
|
| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
|
Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Personal protection: filter respirator for organic gases and vapours.
|
EU Classification Symbol: Xn R: 10-20 S: (2-)-23-24/25 UN Classification UN Hazard Class: 3 UN Pack Group: III | |||||||
| EMERGENCY RESPONSE | SAFE STORAGE | |||||||
|
Transport Emergency Card: TEC (R)-30GF1-III or 30S2293
|
Fireproof. Separated from strong oxidants.
| |||||||
| ||||||||
| |||
| IMPORTANT DATA | |||
|
PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID. CHEMICAL DANGERS: Reacts with oxidants. The substance decomposes on burning producing toxic fumes and irritating fumes. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes, the respiratory tract and the skin. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. | ||
| PHYSICAL PROPERTIES | |||
|
Boiling point: 160°C Melting point: -30°C Relative density (water = 1): 0.89 Solubility in water, g/100 ml at 25°C: 28 Vapour pressure, kPa at 25°C: 0.42 Relative vapour density (air = 1): 4.49 |
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01 Flash point: 60°C c.c. Auto-ignition temperature: 400°C Octanol/water partition coefficient as log Pow: 0.36 | ||
| ENVIRONMENTAL DATA | |||
|
| |||
| NOTES | |||
|
Card has been partly updated in April 2005. See section Physical properties.
| |||
| ADDITIONAL INFORMATION | |||
|
| |||
| |||
| © IPCS, CEC 2004 | |||
See Also:
Toxicological Abbreviations