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PROPAQUIZAFOPICSC: 1271
June 2011
CAS #: 111479-05-12-Isopropylideneamino-oxyethyl (R)-2-(4-(6-chloroquinoxalin-2-yloxy)phenoxy)propionate
(R)-2-(((1-Methylethylidene)amino)oxy)ethyl 2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)propanoate
UN #: 3077

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.        In case of fire in the surroundings, use appropriate extinguishing media.   

 STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!  
  SYMPTOMS ACUTE HAZARDS FIRST AID
Inhalation See Notes.  Use local exhaust or breathing protection.  Fresh air, rest. Seek medical attention if you feel unwell. 
Skin See Notes.  Protective gloves. Protective clothing.  Remove contaminated clothes. Rinse and then wash skin with water and soap. 
Eyes Redness.  Wear safety spectacles.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion See Notes.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Seek medical attention if you feel unwell. 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. 

According to UN GHS Criteria

excl mark;warnenviro;aqua
WARNING
Harmful if inhaled
May be harmful if swallowed
Very toxic to aquatic life with long lasting effects 

Transportation
UN Classification
UN Hazard Class: 9; UN Pack Group: III 

STORAGE
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Store in an area without drain or sewer access. 
PACKAGING
Do not transport with food and feedstuffs. 
PROPAQUIZAFOP ICSC: 1271
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS-TO-BROWN CRYSTALS. 

Physical dangers
 

Chemical dangers
Decomposes on burning. This produces toxic and corrosive fumes including hydrogen chloride and nitrogen oxides. 

Formula: C22H22ClN3O5
Molecular mass: 443.9
Melting point: 62-64°C
Relative density (water = 1): 1.3
Solubility in water, g/100ml at 20°C: 0.06 (very poor)
Vapour pressure at 20°C: negligible
Octanol/water partition coefficient as log Pow: 4.6  


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol. 

Effects of short-term exposure
The substance is mildly irritating to the eyes. 

Inhalation risk
A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered. 

Effects of long-term or repeated exposure
See Notes. 


Occupational exposure limits
 

ENVIRONMENT
The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal. 

NOTES
Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.
If the substance is formulated with solvents also consult the ICSCs of these materials.
Carrier solvents used in commercial formulations may change physical and toxicological properties. 

ADDITIONAL INFORMATION
  EC Classification
 

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    See Also:
       Toxicological Abbreviations