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IMAZALIL
ICSC: 1303
Peer-Review Status: 25.11.1998 Validated
Allyl 1-(2,4-dichlorophenyl)-2-imidazol-1-ylethyl ether
1-(2-(2,4-Dichlorophenyl)-2-(2-propenyloxy)ethyl)-1H-imidazole
Enilconazole 
CAS #: 35554-44-0 RTECS #: NI4776000
EC #: 613-042-00-5
EINECS #: 252-615-0
    Formula: C14H14Cl2N2O
Molecular mass: 297.2

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.  NO open flames.  Use water spray, powder, foam, carbon dioxide. 
EXPLOSION      
 
EXPOSURE      
Inhalation     Fresh air, rest. 
Skin   Protective gloves.  Remove contaminated clothes. Rinse skin with plenty of water or shower. 
Eyes Redness. Pain.  Wear safety goggles.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Nausea.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Refer for medical attention . 

SPILLAGE DISPOSAL
PACKAGING & LABELLING
Sweep spilled substance into covered sealable containers. Carefully collect remainder. Then store and dispose of according to local regulations. Personal protection: chemical protection suit including self-contained breathing apparatus.  Do not transport with food and feedstuffs. 
EC Classification
Symbol: Xn, N; R: 20/22-41-50/53; S: (2)-26-39-60-61 
UN Classification
 
GHS Classification
 

EMERGENCY RESPONSE SAFE STORAGE
  Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Keep in a well-ventilated room. 

IMPORTANT DATA
Physical State; Appearance
LIGHT YELLOW-TO-BROWN CRYSTALLINE MASS (SOLIDIFIED OIL). 

Physical dangers
 

Chemical dangers
Decomposes on distillation or on burning. This produces toxic fumes of nitrogen oxides and chloride. 

Occupational exposure limits
TLV (NOT-ESTABLISHED):. 

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion. 

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying. 

Effects of short-term exposure
The substance is severely irritating to the eyes. 

Effects of long-term or repeated exposure
The substance may have effects on the liver. This may result in impaired functions and tissue lesions. 


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 319-347°C (estimated)
Melting point: 50°C
Relative density (water = 1): 1.2
Solubility in water, g/100ml at 20°C: 0.14
Vapour pressure at 20°C: negligible
Flash point: 192°C
Octanol/water partition coefficient as log Pow: 4.56  
The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use. 

NOTES
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Bromazil, Deccozil, Fecundal, Florasan, Freshgard, Fungaflor, Fungazil, Imaverol, Impala, Magnate, Sanazil are trade names. 

ADDITIONAL INFORMATION
 

IPCS
International
Programme on
Chemical Safety
WHO ILO EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004-2012
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.


    See Also:
       Toxicological Abbreviations
       Imazalil (Pesticide residues in food: 1977 evaluations)
       Imazalil (Pesticide residues in food: 1980 evaluations)
       Imazalil (Pesticide residues in food: 1984 evaluations)
       Imazalil (Pesticide residues in food: 1984 evaluations)
       Imazalil (Pesticide residues in food: 1985 evaluations Part II Toxicology)
       Imazalil (Pesticide residues in food: 1986 evaluations Part II Toxicology)
       Imazalil (Pesticide residues in food: 1991 evaluations Part II Toxicology)
       Imazalil (JMPR Evaluations 2000 Part II Toxicological)
       Imazalil (JMPR Evaluations 2001 Part II Toxicological)
       Imazalil (JMPR Evaluations 2005 Part II Toxicological)