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IMAZALILICSC: 1303
Allyl 1-(2,4-dichlorophenyl)-2-imidazol-1-ylethyl ether
1-(2-(2,4-Dichlorophenyl)-2-(2-propenyloxy)ethyl)-1H-imidazole
Enilconazole
November 1998
CAS #: 35554-44-0
EC Number: 252-615-0

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.    NO open flames.    Use water spray, powder, foam, carbon dioxide.   

   
  SYMPTOMS PREVENTION FIRST AID
Inhalation     Fresh air, rest. 
Skin   Protective gloves.  Remove contaminated clothes. Rinse skin with plenty of water or shower. 
Eyes Redness. Pain.  Wear safety goggles.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Nausea.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: chemical protection suit including self-contained breathing apparatus. Sweep spilled substance into covered sealable containers. Carefully collect remainder. Then store and dispose of according to local regulations. 

According to UN GHS Criteria

 

Transportation
UN Classification
 

STORAGE
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Keep in a well-ventilated room. 
PACKAGING
Do not transport with food and feedstuffs. 
IMAZALIL ICSC: 1303
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
LIGHT YELLOW-TO-BROWN CRYSTALLINE MASS (SOLIDIFIED OIL). 

Physical dangers
 

Chemical dangers
Decomposes on distillation or on burning. This produces toxic fumes of nitrogen oxides and chloride. 

Formula: C14H14Cl2N2O
Molecular mass: 297.2
Boiling point: 319-347°C (estimated)
Melting point: 50°C
Relative density (water = 1): 1.2
Solubility in water, g/100ml at 20°C: 0.14
Vapour pressure at 20°C: negligible
Flash point: 192°C
Octanol/water partition coefficient as log Pow: 4.56  


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion. 

Effects of short-term exposure
The substance is severely irritating to the eyes. 

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying. 

Effects of long-term or repeated exposure
The substance may have effects on the liver. This may result in impaired functions and tissue lesions. 


OCCUPATIONAL EXPOSURE LIMITS
MAK: (inhalable fraction): 2 mg/m3; peak limitation category: I(2); skin absorption (H); pregnancy risk group: C 

ENVIRONMENT
The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use. 

NOTES
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties. 

ADDITIONAL INFORMATION
  EC Classification
Symbol: Xn, N; R: 20/22-41-50/53; S: (2)-26-39-60-61 

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    See Also:
       Toxicological Abbreviations
       Imazalil (Pesticide residues in food: 1977 evaluations)
       Imazalil (Pesticide residues in food: 1980 evaluations)
       Imazalil (Pesticide residues in food: 1984 evaluations)
       Imazalil (Pesticide residues in food: 1984 evaluations)
       Imazalil (Pesticide residues in food: 1985 evaluations Part II Toxicology)
       Imazalil (Pesticide residues in food: 1986 evaluations Part II Toxicology)
       Imazalil (Pesticide residues in food: 1991 evaluations Part II Toxicology)
       Imazalil (JMPR Evaluations 2000 Part II Toxicological)
       Imazalil (JMPR Evaluations 2001 Part II Toxicological)
       Imazalil (JMPR Evaluations 2005 Part II Toxicological)