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BENZYLAMINEICSC: 1338
Aminotoluene
Phenylmethylamine
Benzenemethanamine
Monobenzylamine
October 1999
CAS #: 100-46-9
UN #: 2735
EC Number: 202-854-1

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Flammable. Gives off irritating or toxic fumes (or gases) in a fire.  Above 60°C explosive vapour/air mixtures may be formed.  NO open flames, NO sparks and NO smoking.  Above 60°C use a closed system, ventilation and explosion-proof electrical equipment.  Use water spray, powder, alcohol-resistant foam, carbon dioxide.  In case of fire: keep drums, etc., cool by spraying with water. 

 AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! 
  SYMPTOMS PREVENTION FIRST AID
Inhalation Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing. Symptoms may be delayed. See Notes.  Use ventilation, local exhaust or breathing protection.  Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. 
Skin Pain. Redness. Skin burns. Blisters.  Protective gloves. Protective clothing.  Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . 
Eyes Pain. Redness. Severe deep burns.  Wear face shield.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Burning sensation. Abdominal pain. Shock or collapse.  Do not eat, drink, or smoke during work.  Rinse mouth. Do NOT induce vomiting. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable containers as far as possible. Cautiously neutralize remainder. Then wash away with plenty of water. 

According to UN GHS Criteria

 

Transportation
UN Classification
UN Hazard Class: 8 

STORAGE
Fireproof. Separated from strong oxidants, strong acids and food and feedstuffs. 
PACKAGING
Do not transport with food and feedstuffs. 
BENZYLAMINE ICSC: 1338
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS-TO-YELLOW LIQUID. 

Physical dangers
 

Chemical dangers
Decomposes on burning. This produces toxic fumes including nitrogen oxides. The substance is a medium strong base. Reacts with acids and strong oxidants. 

Formula: C7H9N / C6H5CH2NH2
Molecular mass: 107.2
Boiling point: 185°C
Melting point: 10°C
Relative density (water = 1): 0.98
Solubility in water: miscible
Vapour pressure, Pa at 25°C: 87
Flash point: 60°C
Octanol/water partition coefficient as log Pow: 1.09  


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour and by ingestion. 

Effects of short-term exposure
The substance is corrosive to the eyes, skin and respiratory tract. Inhalation of the vapour may cause lung oedema. See Notes. The effects may be delayed. Medical observation is indicated. 

Inhalation risk
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C. 

Effects of long-term or repeated exposure
 


OCCUPATIONAL EXPOSURE LIMITS
 

ENVIRONMENT
 

NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation is therefore essential.
Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered. 

ADDITIONAL INFORMATION
  EC Classification
Symbol: C; R: 21/22-34; S: (1/2)-26-36/37/39-45 

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    See Also:
       Toxicological Abbreviations