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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Combustible.
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NO open flames.
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In case of fire in the surroundings: use appropriate extinguishing media.
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| EXPLOSION |
Above 75°C explosive vapour/air mixtures may be formed.
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Above 75°C use a closed system, ventilation, and explosion-proof electrical equipment.
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In case of fire: keep drums, etc., cool by spraying with water.
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| EXPOSURE |
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| Inhalation |
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Ventilation.
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Fresh air, rest. Refer for medical attention.
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| Skin |
Redness. Pain.
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Protective gloves. Protective clothing.
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Refer for medical attention.
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| Eyes |
Redness. Pain.
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Safety goggles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
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Do not eat, drink, or smoke during work.
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Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place.
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EU Classification Symbol: Xi R: 36/37/38 S: (2-)-23-24/25-26 UN Classification | |||||||
| EMERGENCY RESPONSE | SAFE STORAGE | |||||||
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Cool.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID CHEMICAL DANGERS: The substance polymerizes rapidly. The substance decomposes on heating or on burning producing toxic and irritating fumes/gases including nitrogen oxides and cyanides. OCCUPATIONAL EXPOSURE LIMITS: TLV: 0.2 ppm as TWA; (ACGIH 2004). MAK: IIb (not established but data is available) (DFG 2004). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is severely irritating to the eyes and the skin. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact may cause skin sensitization. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 54-56°C |
Flash point: 75°C c.c. | ||
| ENVIRONMENTAL DATA | |||
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| NOTES | |||
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Card has been partly updated in April 2005. See section Occupational Exposure Limits.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2004 | |||
See Also:
Toxicological Abbreviations