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SODIUM CHROMATEICSC: 1370
April 2013
CAS #: 7775-11-3Disodium chromate (VI)
Chromic acid, disodium salt
Disodium chromium tetraoxide
UN #: 3288
EINECS #: 231-889-5

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Not combustible but enhances combustion of other substances.    NO contact with combustible substances.    In case of fire in the surroundings, use appropriate extinguishing media.   

 PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! 
  SYMPTOMS ACUTE HAZARDS FIRST AID
Inhalation Burning sensation. Sore throat. Cough. Wheezing. Laboured breathing.  Use closed system or ventilation.  Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. 
Skin Redness. Pain. Skin burns.  Protective gloves. Protective clothing.  First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer for medical attention . 
Eyes Redness. Pain. Blurred vision. Severe deep burns.  Wear face shield or eye protection in combination with breathing protection.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Nausea. Vomiting. Abdominal pain. Burning sensation. Diarrhoea. Shock or collapse.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: complete protective clothing including self-contained breathing apparatus. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. 

According to UN GHS Criteria

flam circleskull;toxiccorrcancer;health hazenviro;aqua
DANGER
May intensify fire; oxidizer
Toxic if swallowed
Harmful in contact with skin
Fatal if inhaled
Causes severe skin burns and eye damage
May cause allergy or asthma symptoms or breathing difficulties if inhaled
May cause an allergic skin reaction
May cause genetic defects
May cause cancer
May damage fertility or the unborn child
Causes damage to kidneys
Causes damage to the nose through prolonged or repeated exposure if inhaled
Very toxic to aquatic life with long lasting effects 

Transportation
UN Classification
UN Hazard Class: 6.1; UN Pack Group: II 

STORAGE
Provision to contain effluent from fire extinguishing. Separated from combustible substances, reducing agents and food and feedstuffs. Dry. Well closed. Store in an area without drain or sewer access. 
PACKAGING
Do not transport with food and feedstuffs. 
SODIUM CHROMATE ICSC: 1370
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
YELLOW HYGROSCOPIC CRYSTALS. 

Physical dangers
 

Chemical dangers
The solution in water is a weak base. The substance is a strong oxidant. It reacts with combustible and reducing materials. 

Formula: Na2CrO4
Molecular mass: 162
Melting point: 762°C
Density: 2.7 g/cm³
Solubility in water, g/100ml at 20°C: 53 (good) 


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion. 

Effects of short-term exposure
The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. The substance may cause effects on the kidneys and liver. This may result in tissue lesions. 

Inhalation risk
A harmful concentration of airborne particles can be reached quickly when dispersed. 

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization. Repeated or prolonged inhalation may cause asthma. Repeated or prolonged inhalation may cause nasal ulceration. This may result in perforation of the nasal septum. The substance may have effects on the kidneys. This may result in kidney impairment. This substance is carcinogenic to humans. Animal tests show that this substance possibly causes toxicity to human reproduction or development. 


Occupational exposure limits
TLV: 0.05 mg/m3, ppm, as TWA; A1 (confirmed human carcinogen); BEI issued.
MAK: (inhalable fraction): skin absorption (H); sensitization of skin (SH); carcinogen category: 1; germ cell mutagen group: 2 

ENVIRONMENT
The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment. 

NOTES
Do NOT take working clothes home.
Rinse contaminated clothing with plenty of water because of fire hazard.
Anyone who has shown symptoms of asthma due to this substance should avoid all further contact.
The symptoms of asthma often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
The recommendations on this Card also apply to sodium chromate tetrahydrate (CAS No. 10034-82-9). 

ADDITIONAL INFORMATION
  EC Classification
Symbol: T+, N; R: 45-46-60-61-21-25-26-34-42/43-48/23-50/53; S: 53-45-60-61; Note: E, 3 

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    See Also:
       Toxicological Abbreviations