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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Flammable.
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NO open flames, NO sparks, and NO smoking.
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Powder, water spray, foam, carbon dioxide.
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| EXPLOSION |
Above 53°C explosive vapour/air mixtures may be formed.
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Above 53°C use a closed system, ventilation.
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In case of fire: keep drums, etc., cool by spraying with water.
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| EXPOSURE |
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| Inhalation |
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
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| Skin |
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Protective gloves.
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Remove contaminated clothes. Rinse skin with plenty of water or shower.
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| Eyes |
Redness.
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Safety goggles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
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Do not eat, drink, or smoke during work.
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Rinse mouth.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Remove all ignition sources. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Then wash away with plenty of water.
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EU Classification R: 10-67 S: (2-)-24 UN Classification UN Hazard Class: 3 UN Pack Group: III | |||||||
| EMERGENCY RESPONSE | SAFE STORAGE | |||||||
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Transport Emergency Card: TEC (R)-30GF1-III
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Fireproof.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. CHEMICAL DANGERS: On combustion, forms acetic acid fumes. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. |
INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is mildly irritating to the eyes. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 160°C Melting point: -89°C Relative density (water = 1): 0.98 Solubility in water, g/100 ml at 20°C: 9.5 Vapour pressure, kPa at 20°C: 0.227 |
Flash point: 53°C c.c. Auto-ignition temperature: 325°C Explosive limits, vol% in air: 1.0-9.8 Octanol/water partition coefficient as log Pow: 0.76 | ||
| ENVIRONMENTAL DATA | |||
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| NOTES | |||
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2004 | |||
See Also:
Toxicological Abbreviations