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N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-p-PHENYLENEDIAMINEICSC: 1635
N-(4-Methyl-2-pentyl)-N'-phenyl-1,4-diaminobenzene
1,4-Benzenediamine, N-(1,3-dimethylbutyl)-N'-phenyl-
p-Phenylenediamine, N-(1,3-dimethylbutyl)-N'-phenyl-
6PPD
October 2006
CAS #: 793-24-8
UN #: 3077
EC Number: 212-344-0

  ACUTE HAZARDS PREVENTION FIRE FIGHTING
FIRE & EXPLOSION Combustible. Gives off irritating or toxic fumes (or gases) in a fire.    NO open flames.    Use water spray, powder.   

 STRICT HYGIENE!  
  SYMPTOMS PREVENTION FIRST AID
Inhalation Cough.  Use local exhaust or breathing protection.  Fresh air, rest. 
Skin Redness.  Protective clothing. Protective gloves.  Remove contaminated clothes. Rinse and then wash skin with water and soap. 
Eyes Redness.  Wear safety goggles.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion   Do not eat, drink, or smoke during work.  Rinse mouth. Refer for medical attention . 

SPILLAGE DISPOSAL CLASSIFICATION & LABELLING
Personal protection: protective gloves and particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. 

According to UN GHS Criteria

excl mark;warnenviro;aqua
WARNING
Causes eye irritation
Causes mild skin irritation
May cause allergic skin reaction
Very toxic to aquatic life 

Transportation
UN Classification
UN Hazard Class: 9; UN Pack Group: III 

STORAGE
Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access. Separated from strong oxidants. 
PACKAGING
 
N-(1,3-DIMETHYLBUTYL)-N'-PHENYL-p-PHENYLENEDIAMINE ICSC: 1635
PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
BROWN-TO-VIOLET SOLID IN VARIOUS FORMS. TURNS DARK BROWN ON EXPOSURE TO LIGHT. 

Physical dangers
 

Chemical dangers
Decomposes on burning. This produces toxic fumes including nitrogen oxides. Reacts with strong oxidants. 

Formula: C18H24N2
Molecular mass: 268.4
Boiling point: 370°C (calculated)
Melting point: 45-48°C
Density: 1.02 g/cm³
Solubility in water, g/100ml at 20°C: 0.01
Vapour pressure at 25°C: negligible
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Flash point: 200°C c.c.
Auto-ignition temperature: ~500°C
Octanol/water partition coefficient as log Pow: 5.4  


EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by ingestion. 

Effects of short-term exposure
The substance is mildly irritating to the eyes and skin. 

Inhalation risk
A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered. 

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization. 


OCCUPATIONAL EXPOSURE LIMITS
MAK: (inhalable fraction): 2 mg/m3; peak limitation category: II(2); sensitization of skin (SH); pregnancy risk group: C 

ENVIRONMENT
The substance is very toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. 

NOTES
Do NOT take working clothes home. 

ADDITIONAL INFORMATION
  EC Classification
 

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    See Also:
       Toxicological Abbreviations