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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Carbon dioxide, powder, water spray.
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| EXPLOSION |
Above 87°C explosive vapour/air mixtures may be formed.
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Above 87°C use a closed system, ventilation.
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| EXPOSURE |
See NOTES.
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| Inhalation |
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest.
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| Skin |
Redness.
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Protective gloves.
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Rinse and then wash skin with water and soap.
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| Eyes |
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Safety goggles.
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Rinse with plenty of water (remove contact lenses if easily possible).
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| Ingestion |
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Do not eat, drink, or smoke during work.
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Rinse mouth.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Remove vapour with fine water spray.
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| EMERGENCY RESPONSE | STORAGE | |||||||
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Provision to contain effluent from fire extinguishing. Separated from strong bases, strong oxidants. Cool. Keep in a well-ventilated room. Store in an area without drain or sewer access.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: As a result of flow, agitation, etc., electrostatic charges can be generated. CHEMICAL DANGERS: The substance decomposes on heating producing carbon monoxide, chlorine, hydrogen chloride and vinyl chloride. Reacts violently with strong oxidants and strong bases. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. |
INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is mildly irritating to the skin. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point at 101.3kPa: 200°C Melting point: -13.5°C Density: 1.25 g/cm³ Solubility in water, g/100 ml at 20°C: (very poor). Vapour pressure, kPa at 50°C: 0.4 Relative vapour density (air = 1): 5.56 |
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02 Flashpoint: 87°C c.c. Explosive limits, vol% in air: 1.9-4.5 Octanol/water partition coefficient as log Pow: 4.24 | ||
| ENVIRONMENTAL DATA | |||
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The substance is toxic to aquatic organisms. It is strongly advised that this substance does not enter the environment.
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| NOTES | |||
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Health effects of exposure to the substance have not been investigated adequately.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations