ICSC 0097 - AMINOCARB

AMINOCARB	ICSC: 0097 (April 2009)
4-Dimethylamino-m-tolyl N-methylcarbamate 4-Dimethylamine m-cresyl methylcarbamate

CAS #: 2032-59-9

UN #: 2757

EC Number: 217-990-7

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion if formulations contain flammable/explosive solvents.	NO open flames.	Use powder, water spray, foam, carbon dioxide.

AVOID ALL CONTACT! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	See Ingestion.	Use local exhaust or breathing protection.	Fresh air, rest. Half-upright position. Refer for medical attention. See Notes.
Skin	MAY BE ABSORBED! See Ingestion.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention . See Notes.
Eyes		Wear face shield or eye protection in combination with breathing protection.	Rinse with plenty of water (remove contact lenses if easily possible). Refer for medical attention.
Ingestion	Cough. Muscle twitching. Dizziness. Pupillary constriction. Muscle cramps. Excessive salivation. Laboured breathing. Nausea. Vomiting. Diarrhoea. Unconsciousness.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer for medical attention . See Notes.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria DANGER Fatal if swallowed Toxic in contact with skin Causes damage to nervous system Causes damage to the nervous system through prolonged or repeated exposure Very toxic to aquatic life Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: II
STORAGE
Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access. Separated from food and feedstuffs.
PACKAGING
Do not transport with food and feedstuffs. Marine pollutant.

AMINOCARB

ICSC: 0097

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance WHITE CRYSTALS. Physical dangers Chemical dangers Decomposes on heating. This produces toxic and irritating fumes including nitrogen oxides.	Formula: C₁₁H₁₆N₂O₂ Molecular mass: 208.3 Melting point: 93°C Solubility in water, g/100ml at 20°C: 0.09 (very poor) Vapour pressure, Pa at 20°C: 0.0023 Relative vapour density (air = 1): 7.2 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00 Octanol/water partition coefficient as log Pow: 1.73

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
WHITE CRYSTALS.

Physical dangers

Chemical dangers
Decomposes on heating. This produces toxic and irritating fumes including nitrogen oxides.

Formula: C₁₁H₁₆N₂O₂
Molecular mass: 208.3
Melting point: 93°C
Solubility in water, g/100ml at 20°C: 0.09 (very poor)
Vapour pressure, Pa at 20°C: 0.0023
Relative vapour density (air = 1): 7.2
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Octanol/water partition coefficient as log Pow: 1.73

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body through the skin and by ingestion. Effects of short-term exposure Cholinesterase inhibition. The substance may cause effects on the nervous system. Exposure could cause death. The effects may be delayed. Medical observation is indicated.	Inhalation risk A harmful concentration of airborne particles can be reached quickly on spraying. Effects of long-term or repeated exposure The substance may have effects on the nervous system.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body through the skin and by ingestion.

Effects of short-term exposure
Cholinesterase inhibition. The substance may cause effects on the nervous system. Exposure could cause death. The effects may be delayed. Medical observation is indicated.

Inhalation risk
A harmful concentration of airborne particles can be reached quickly on spraying.

Effects of long-term or repeated exposure
The substance may have effects on the nervous system.

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is toxic to aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.

NOTES
Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home.

ADDITIONAL INFORMATION

EC Classification
Symbol: T, N; R: 24/25-50/53; S: (1/2)-28-36/37-45-60-61

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    See Also:
       Toxicological Abbreviations
       Aminocarb (Pesticide residues in food: 1978 evaluations)
       Aminocarb (Pesticide residues in food: 1979 evaluations)