ICSC 0469 - EPTC

EPTC	ICSC: 0469 (March 1996)
S-Ethyl dipropylthiocarbamate Carbamothioic acid, dipropyl-, S-ethyl ester S-Ethyl dipropylcarbamothioate S-Ethyl-N,N-dipropylthiocarbamate

CAS #: 759-94-4

UN #: 2992

EC Number: 212-073-8

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Use water spray, foam, powder, carbon dioxide.

PREVENT GENERATION OF MISTS! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Dizziness. Headache. Nausea.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	Redness.	Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness.	Wear safety spectacles or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	See Inhalation.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Rest. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Do NOT wash away into sewer. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: III
STORAGE
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Ventilation along the floor.
PACKAGING
Do not transport with food and feedstuffs.

EPTC

ICSC: 0469

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers Chemical dangers Decomposes on heating and on burning. This produces toxic fumes including nitrogen oxides and sulfur oxides.	Formula: C₉H₁₉NOS / CH₃CH₂SC(O)N(CH₂CH₂CH₃)₂ Molecular mass: 189.3 Boiling point: 232°C Relative density (water = 1): 0.95 Solubility in water: none Vapour pressure, Pa at 25°C: 4.5 Relative vapour density (air = 1): 6.5 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00 Flash point: 116°C o.c. Octanol/water partition coefficient as log Pow: 3.20

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers

Chemical dangers
Decomposes on heating and on burning. This produces toxic fumes including nitrogen oxides and sulfur oxides.

Formula: C₉H₁₉NOS / CH₃CH₂SC(O)N(CH₂CH₂CH₃)₂
Molecular mass: 189.3
Boiling point: 232°C
Relative density (water = 1): 0.95
Solubility in water: none
Vapour pressure, Pa at 25°C: 4.5
Relative vapour density (air = 1): 6.5
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Flash point: 116°C o.c.
Octanol/water partition coefficient as log Pow: 3.20

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation, through the skin and by ingestion. Effects of short-term exposure The substance may cause effects on the central nervous system.	Inhalation risk A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster. Effects of long-term or repeated exposure

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

Effects of short-term exposure
The substance may cause effects on the central nervous system.

Inhalation risk
A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.

Effects of long-term or repeated exposure

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is harmful to aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.

NOTES
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. The relation between odour and the occupational exposure limit cannot be indicated.

ADDITIONAL INFORMATION

EC Classification
Symbol: Xn; R: 22; S: (2)-23

All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.

    See Also:
       Toxicological Abbreviations