|THIOPHOSPHORYL CHLORIDE||ICSC: 0581 (March 1998)|
| CAS #: 3982-91-0
| UN #: 1837
|EC Number: 223-622-6
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Not combustible but forms flammable gas on contact with water or damp air. Risk of fire and explosion on contact with water or moisture.||NO open flames, NO sparks and NO smoking. NO contact with water or moisture.||Use powder, carbon dioxide. NO water. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water. Combat fire from a sheltered position.|
|AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Burning sensation. Cough. Headache. Laboured breathing. Shortness of breath. Sore throat. Unconsciousness. Vomiting. Wheezing. Symptoms may be delayed. See Notes.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.|
|Skin||Redness. Skin burns. Pain. Blisters.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .|
|Eyes||Redness. Pain. Loss of vision. Severe deep burns.||Wear safety goggles, face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Burning sensation. Nausea. Shock or collapse. Further see Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Refer for medical attention . See Notes.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. NEVER direct water jet on liquid.||
According to UN GHS Criteria
|Fireproof. Provision to contain effluent from fire extinguishing. Cool. Dry.|
|THIOPHOSPHORYL CHLORIDE||ICSC: 0581|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
|This substance may be hazardous to the environment. Special attention should be given to water quality.|
|Reacts violently with fire extinguishing agents such as water or foam.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.
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See Also: Toxicological Abbreviations