|DEMETON (MIXED ISOMERS)||ICSC: 0861 (September 2002)|
| CAS #: 8065-48-3
| UN #: 3018
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Liquid formulations containing organic solvents may be flammable.||NO open flames.||Use water spray, foam, carbon dioxide, alcohol-resistant foam, dry powder.|
|PREVENT GENERATION OF MISTS! AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Convulsions. Dizziness. Laboured breathing. Nausea. Vomiting. Pupillary constriction, muscle cramp, excessive salivation. Sweating. Unconsciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Further see Inhalation.||Protective clothing. Protective gloves.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||MAY BE ABSORBED! Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal cramps. Diarrhoea. Vomiting. See Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Give a slurry of activated charcoal in water to drink. See Notes. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Separated from strong oxidants and food and feedstuffs. Keep in a well-ventilated room. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.|
|Do not transport with food and feedstuffs.|
|DEMETON (MIXED ISOMERS)||ICSC: 0861|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: (C2H5O)2PS.OCH2CH2SC2H5 / (C2H5O)2PO.SCH2CH2SC2H5
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.05 mg/m3, as TWA; (skin); BEI issued.
MAK: skin absorption (H)
|The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to birds, bees and mammals. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.|
|This substance is a mixture of two isomers: Demeton-O and Demeton-S (see ICSC 0864).
Do NOT take working clothes home.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Depending on the degree of exposure, periodic medical examination is suggested.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Symbol: T+, N; R: 27/28-50; S: (1/2)-28-36/37-45-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations