Annex 1 INDEX TO DOCUMENTATION AND SUMMARY OF RECOMMENDATIONS CONCERNING ACCEPTABLE DAILY INTAKES, TOLERANCES, PRACTICAL RESIDUE LIMITS, AND GUIDELINE LEVELS AS OF NOVEMBER 1972 Further details concerning the recommendations will be found in the original documents referred to in the second column. Explanatory notes are given at the end of this table. Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made acrylonitrile 1965c aldrin 1967b, 0.0001 See also dieldrin. 1968b allethrin 1965b arsenic (as calcium 1969b or lead arsenate) azinphos-methyl 1959b, 0.0025 Apricots, grapes 4 a Date for review postponed to 1973b Other fruit 1 a 1973 to provide more time for Vegetables 0.5 a experiment. benomyl 1973a BHC (mixture of 1969b isomers) Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made binapacryl 1970b 0.0025 Peaches, cherries 1 Apples, pears, grapes 0.5 Plums 0.3 Nectarines 0.2 biphenyl See diphenyl. 2-biphenylol See 2-phenylphenol. bromide (inorganic 1969b 1 Raw cereals, wholemeal 50 Recommendations relate form, derived from 1970b, flour exclusively to inorganic bromine-containing 1972a,b bromide, not to bromine fumigants and present as unchanged fumigant. other sources) Other recommendations from previous meetings held in abeyance pending further data on normal background bromide levels and on residues from supervised trials (see FAO/WHO 1972a and 1972b). bromomethane 19671b, Nuts, peanuts 100 f Figures relate only to 1968b, Raw cereals, cocoa beans 50 f unchanged fumigant (see also 1972a,b Dried fruit 20 f bromide). See also FAO/WHO Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made Milled cereal products 10 g 1972a pp. 12-16. Previously Bread, other cooked cereal listed as methyl bromide. products, cocoa products, dried fruit, nuts, peanuts 0.5 h bromophos 1973b 0.006 e *Olives, olive oil 5 e The tolerance for wheat is *Apples, lamb's lettuce, based on residues likely to leeks, radishes 2 e be found at harvest. *Pears, plums, red currants, carrots, celery, French beans, savoy cabbage, spinach 1 e *Blackberries, black currants, cherries, gooseberries, peaches, strawberries, lettuce, sugarbeet (roots) 0.5 e *Fat of meat of sheep 0.5 e *Rape seed, rape seed oil, wheat 0.2 e *Broccoli, red cabbage, cabbage, cauliflower, cucumbers, kohlrabi, onions, peas 0.1 e *Milk (whole) 0.02 # Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made bromophos-ethyl 1973b 0.003 c *Apples, pears, plums, carrots, spinach 2 c *Fat of meat of cattle 2 c *Red currants, Brussels sprouts 1 c *Cherries (sweet), gooseberries, peaches, celeriac, rape seed oil 0.5 c *Black currants, lettuce 0.2 c *Strawberries, rape seed, cabbage 0.1 c *Kohlrabi, French beans 0.05 c *Beans (without pod), cauliflower, onions, sugarbeet 0.02 # *Milk (whole) 0.02 # calcium arsenate See lead arsenate 1969b. camphechlor 1969b Listed as toxaphene, 1969b. captafol 1970b 0.05 a Peaches 15 a Recommendations relate only Cherries (sour) 10 a to parent substance. Referred Cherries (sweet) 2 a to as difolatan in FAO/WHO Tomatoes 5 a 1969a, p. 18. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made Melons (whole) 2 a Cucumbers (whole) 1 a Apricots 0.5 a Plums 0.2 a captan 1970b 0.125 a Apples, cherries 40 a Pears 30 a Apricots 20 a Citrus fruit, peaches, plums, rhubarb, tomatoes 15 a Strawberries, raspberries, cranberries, cucumbers, lettuce, green beans, peppers 10 a Raisins 5 a carbaryl 1957b, 0.01 a *Apricots 10 a Earlier tolerances reviewed at 1968b, Blackberries, boysenberries, 1969 Meeting in light of Codex 1969b, nectarines, peaches, comments. Tolerance on whole 1970b, raspberries, asparagus, milk temporarily withdrawn 1971b okra, leafy vegetables (see FAO/WHO 1970b). Apricots (except brassicas), unintentionally omitted from nuts (whole), Annex 1 of FAO/WHO 1971a olives (fresh) 10 a and FAO/WHO 1972a. Blueberries, citrus fruit, strawberries 7 a Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made Apples, bananas (pulp), grapes, beans, peas (inciuding pod), brassicas, tomatoes, peppers, aubergines, poultry (skin) 5 a Poultry (total) (edible portions) 0.5 a Cucurbits (including melons) 3 a Rice 2.5 a Cottonseed (whole), sweet corn (kernels), nuts (shelled), olives (processed), meat of cattle, goats, and sheep 1 a Potatoes 0.2 a carbon disulfide 1965c, *Raw cereals 10 f See also FAO/WHO 1972a, p. 1968b, *Milled cereal products 2 g 12-16. Errata carbon disulfide 1970a, *Bread and other cooked figures, FAO/WHO 1972a, p. 1972a,b cereal products 0.5 h 26. See also ibid., p. 14 and FAO/WHO 1972b. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made carbon 1965c, Raw cereals 50 f See also FAO/WHO 1972a, p. tetrachloride 1968b, Milled cereal products 10 g 12-16. 1970a, Bread and other cooked 1972b cereal products 0.05 h carbophenothion 1973b 0.005 d *Lemons 5 d Tolerances apply to the total *Spinach 2 d residue, comprising *Fat of meat of cattle and carbophenothion, its sulfoxide sheep 1 d and sulfone, together with *Apricots, nectarines, their corresponding oxygen peaches, prunes, grapefruit, analogues, if present, limes, oranges 1 d expressed as carbophenothion. *Apples, pears, broccoli, Brussels sprouts, cauliflower 0.5 d *Olive oil 0.2 d *Olives (fresh), sugarbeet 0.1 d *Milk and milk products (fat basis) 0.1 d *Potatoes, rape seed 0.02 # *Walnuts and pecans (shelled) 0.02 # chinomethionate 1969b Listed in FAO/WHO 1969b as oxythioquinox, subsequently re-named. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made chlorbenside 1965b 0.01 chlordane 1968b, 0.001 Potatoes, sweet potatoes, Expressed as the sum of the 1970b, rutabagas, turnips, cis- and trans-isomers in 1971b, parsnips, sugarbeet, plant products and as the sum 1973b radishes 0.3 of cis- and trans-isomers and Asparagus, broccoli, oxychlordane in animal Brussels sprouts, products. Tolerances apply to cabbage, celery, residues resulting from soil cauliflower, mustard or seed treatments apart from greens, spinach, Swiss that for cotton seed oil. chard, lettuce 0.2 Tolerance levels for peppers Cantaloupes, cucumbers, and pimentos were established pumpkins, squash, at the 1969 meeting. The watermelons 0.1 figures were not given in FAO/ Almonds, bananas, figs, WHO 1971b. The 1972 meeting filberts, guavas, mangoes, reviewed available data and olives, passion fruit, confirmed tolerances for these papayas, pecans, crops. pomegranates, pineapples, strawberries, walnuts 0.1 Beans, peas, aubergines, tomatoes, collards (= coleworts) 0.02 *Peppers, pimentos 0.02 Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made Wheat, rye, oats, rice (polished), maize, popcorn, sorghum 0.05 Citrus, pome, and stone fruits 0.02 Crude soybean and linseed oils 0.5 Crude cottonseed oil 0.1 Edible cottonseed oil 0.02 Edible soyhean oil 0.02 Milk and milk products (fat basis) 0.05 Fat of meat and poultry 0.05 Eggs (shell-free) 0.02 chlorfenson 1965b 0.01 chlorfenvinphos 1972b 0.002 Carrots, celery 0.4 Expressed as the sum of the *Fat of meat 0.2 alpha and beta isomers of Milk and milk products chlorfenvinphos. (fat basis) 0.2 Cauliflower, radish, horseradish, tomatoes 0.1 Brussels sprouts, cabbage, broccoli, swedes, turnips, potatoes, sweet potatoes, Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made onions, leeks, aubergines, mushrooms, peanuts (shelled), maize, wheat (grain), cottonseed, rice (raw and polished) 0.05 chlormequat 1971b, 0.05 *Oats, rye 5 Residue levels in FAO/WHO 19731, *Wheat, pears 3 1972b now changed to *Grapes, raisins, and other tolerances. dried vine fruit 1 *Milk and milk products 0.1 # chlorobenzilate 1969b, 0.02 *Apples, pears, grapes 2 1973b *Citrus fruit, cantaloupes, melons 1 Almonds and walnuts (shelled) 0.2 *Tomatoes 0.2 *Milk (whole) 0.05 # chlorodimeform 1972b 0,01 Pears, peaches, prunes 5 c Expressed as the sum of Apples grapes, plums, chlorodimeform and its strawberries 3 c metabolites determined as Cherries, citrus fruit, 4-chloro-o-toluldine and brassicas, cottonseed oil expressed as chlorodimeform. (crude and refined), Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made cottonseed 2 c Beans 0.5 c Fat, meat, and meat products of cattle 0.5 c Milk (whole) 0.05 c Milk products 0.5 c chloropicrin 1965c chloropropylate 1969b, *Apples, pears, citrus fruit 3 The temporary ADI established 1973b *Tomatoes, cantaloupes 1 at the 1968 meeting withdrawn (see section 3.4 of FAO/WHO 1973a). chlorpropham 1965b See also section 2.2 of FAO/ WHO 1973a). chlorpyrifos 1973b 0.0015 *Fat of meat of cattle 2 *Apples, chinese cabbage, grapes, kale 1 *Pears, carrots, tomatoes 0.5 *Beans, aubergines, peppers, raspberries 0.2 *Fat of meat of sheep and of poultry 0.2 Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made *Lettuce, sugarbeet, rice (in husk) 0.1 *Celery, cottonseed, cottonseed oil (crude), mushrooms, onions 0.05 *Cauliflower, red cabbage, potatoes 0.01 # *Milk (fat basis) 0.01 # Chlorthion 1965b coumaphos 1969b, 0.0005 c *Fat of meat of cattle 1 c To be determined as 1973b *Poultry 1 c coumaphos and oxygen analogue *Fat of meat of sheep, pigs, and expressed as coumaphos. and goats 0.5 c *Milk and milk products (fat basis) 0.5 c Eggs (shell-free) 0.05 c crufomate 1969b, 0.1 *Meat 1 Qualification "(fat basis)" in 1973b *Milk (whole) 0.05 previous recommendation for meat now deleted. 2,4-D 1971b, 0.3 *Barley, oats, rye, wheat 0.02 Erratum FAO/WHO 1972a, p. 28. 1972b Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made DDT 1967b, 0.005 Apples, apricots, pears, ADI is "conditional". 1968b, (see peaches, small fruits Tolerance on fish withdrawn at 1969b, remarks) (except strawberries), 1969 Meeting. 1970b, vegetables (except root Limits apply to DDT, DDD, and 1973a vegetables), fat of meat DDE singly or in combination. and poultry 7 Tolerances subject to regular review. Cherries, plums, citrus fruit, tropical fruit 3.5 Strawberries, nuts (shelled), root vegetables 1 *Milk and milk products (fat basis) 1.25 Eggs (shell-free) 0.5 demeton 1965b, 0.0025 1968b diazinon 1965b, 0.002 Olives and olive oil 2 Residues to be determined and 1967b, Cherries, citrus fruit, expressed as the parent 1968b, peaches 0.7 compound. Residues decline 1969b, Other fruit 0.5 rapidly during storage and 1971b Leafy vegetables 0.7 shipment; the tolorances are Other vegetables 0.5 based on residues likely to be Sweet corn (kernels and found at harvest or slaughter cob with husks removed) 0.7 (see FAO/WHO 1971b). Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made Cottonseed, safflower seed, sunflower seed 0.5 Almonds, filberts, pecans, peanuts, walnuts (shelled) 0.5 Rice (polished), barley, wheat 0.1 Fat at meat of cattle, sheep, and pigs 0.7 1,2-dibromoethane 1967b, Raw cereals 20 f See also FAO/WHO 1972a, p. 1968b, Milled cereal products 5 g 12-16. Analytical method must 1970a, Bread and other cooked identify residue, because 1972b cereal products 0.1 h guideline level refers to original fumigant. Previously listed as ethylene dibromide. dichlofluanid 1970b 1,2-dichloroethane 1965c, Raw cereals 50 f See also FAO/WHO 1972a, p. 1962b, Milled cereal products 10 g 12-16. Previously listed as 1970a, Bread and other cooked ethylene dichlaride. 1972b cereal products 0.1 h Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made dichlorvos 1967b, 0.004 Cocoa beans 5 The tolerances are based on 1968b, Coffee beans, soybeans, residues likely to be found at 1970b, lentlis, peanuts 2 harvest or slaughter. Residues 1971b Raw grain (barley, maize, decline rapidly during storage oats, rice, rye, sorghum, or shipment (see FAO/WHO wheat, etc.) 2 1968b, 1971b). Milled products from raw The tolerance for grain 0.5 "miscellaneous food items, not Lettuce 1 otherwise specified", for Fresh vegetables (except example bread, cakes, cheese, lettuce) 0.5 cooked meats, etc., is Tomatoes, mushrooms 0.5 intended to cover residues Fresh fruit (apples, pears, resulting from usage of peaches, strawberries, dichlorvos for pest control etc.) 0.1 purposes in storage, in Meat of cattle, sheep, warehouses, shops, etc. goats, pigs, and poultry 0.05 Eggs (shell-free) 0.05 Milk (whole) 0.02 Miscellaneous food items not otherwise specified 0.1 dicofol 1969b, 0.025 Fruit, vegetables 5 1971b *Hops (dried), tea (dry, manufactured) 5 Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made dieldrin 1967b, 0.0001 Asparagus, broccoli, Practical residue limit for 1968b, Brussels sprouts, shell free eggs is equivalent 1969b, cabbage, cauliflower, to 0.25 mg/kg in egg yolk. 1970b, cucumbers, aubergines, Limits apply to aldrin and 1971b horseradish, onions, dieldrin singly or together parsnips, peppers, and expressed as dioldrin. pimentos, radishes, radish tops 0.1 Fruit (other than citrus) 0.1 Citrus fruit 0.05 Rice (in husk) 0.02 Potatoes 0.2 Carrots, lettuce, fat of meat 0.2 Milk and milk products (fat basis) 0.15 Raw cereals (other than rice) 0.02 Eggs (shell-free) 0.1 dimethoate 1968b, 0.02 Tree fruit (including citrus) 2 Residues to be determined as 1971 b Tomatoes, peppers 1 dimethoate and its oxygen Other vegetables 2 analogue and expressed as dimethoate. dimethrin 1965b Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made dinocap 1970b dioxathion 1969b, 0.0015 *Pome fruit, (apples, pears, Residues of cis- and trans 1973b and quinces) 5 isomers of principal active *Citrus fruit 3 ingredient to be determined *Grapes 2 and expressed as sum of both. *Fat of meat of cattle, Tolerances no longer sheep, goats, and pigs 1 temporary. *Milk and milk products (fat basis) 0.2 *Stone fruit (apricots, cherries, peaches, prunes, and plums) 0.1 # diphenyl 1967b, 0.125 Citrus fruit 110 1968b diphenylamine 1970b 0.025 Apples 10 diquat 1971b, 0.005 *Barley, poppy seed, rice Tolerances no longer 1973b (in husk) 5 temporary. *Rape seed, sorghum, ADI equivalent to 0.0036 wheat 2 expressed as diquat ion. *Cottonseed 1 Residues expressed as diquat *Beans, sunflower seed 0.5 ion. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made *Rice (polished), potatoes, wheat flour 0.2 *Onions, maize, sugarbeet, peas 0.1 *Cottonseed oil 0.1 Rape, sesame, and sunflower oils 0.1 *Other vegetable crops 0.05 # *Milk (whole) 0.01 # *Meat and meat products 0.05 # dithiocarbamates, 1965b, 0.025 b ADI applies to parent dimethyl 1958b, compound or to sum or residues (ferbam, thiram, 1971 b of all compounds present. and ziram) To be reviewed in 1974, not 1972 as recorded in Annex 1, FAO/WHO 1971a. dithiocarbamates, 1965b, 0.025 b ADI applies to parent compound ethylenebis 1968b, or to sum of residues of (mancozeb, maneb, 1971b all compounds present (see and zineb, mancozeb). including zineb To be reviewed in 1974, not derived from nabam 1972 as recorded in Annex 1, plus zinc sulfate) FAO/WHO 1971a. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made DNOC 1965b endosulfan 1968b, 0.0075 Tea (dry, manufactured) 30 To be measured and reported 1969b, Fruit, vegetables 2 as total endosulfan A and B 1972b Cottonseed 0.5 and endosulfan sulfate. Cottonseed oil (crude) 0.2 Rice (in husk) 0.1 endrin 1965b, 0.0002 Cottonseed, cottonseed All recommendations are total 1971b oil (crude) 0.1 figures for endrin plus delta- *Corn (sweet) 0.02 keto-endrin. Apples, barley, rice Erratum p. 31 FAO/WHO 1971a. (husked and/or polished), A tolerance of 0.02 was sorghum, wheat 0.02 established for sweet corn Edible cottonseed oil 0.02 (see FAO/WHO 1971b) but Milk and milk products not for maize oil, which (fat basis) 0.02 is deleted. Fat of poultry 1 Eggs (shell-free) 0.2 ethion 1969b, 0.005 *Tea (dry, manufactured) 7 Residues to be determined as 1970b, *Apples, grapes, lemons, ethion and its oxygen analogue 1973b limes, oranges, plums, and expressed as ethion. prunes, strawberries 2 Tolerances no longer *Nectarines, peaches, pears 1 temporary. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made *Apricots, cherries 0.1 # General recommendations for *Almonds, chestnuts, fruit and vegetables filberts, pecans, withdrawn. walnuts (shelled) 0.1 # *Beans, melons, tomatoes 2 *Aubergines, garlic, onions, pimentos, peppers 1 *Cucumbers, squash 0.5 *Cottonseed 0.5 *Maize (grain) 0.05 # *Fat of meat of cattle 2.5 *Edible offal of cattle 0.75 *Fat of meat and edible offal of goats, horses, pigs, poultry, and sheep 0.2 # *Milk and milk products 0.5 # *Eggs (shell-free) 0.2 # ethoxyquin 1970b 0.06 Apples, pears 3 ADI and tolerances erroneously designated as temporary in Appendix 1, FAO/WHO 1970a. ethylene dibromide See 1,2-dibromoethane. ethylene dichloride See 1,2-dichloroethane. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made ethylene oxide 1965c, 1969b, 1970a, 1972b fenchlorphos 1969b, 0.01 *Fat of meat of cattle, Residues of fenchlorphos and 1973b goats, and sheep 10 oxygen analogues to be *Fat of meat of pigs 2 expressed as fenchlorphos. *Milk and milk products Tolerances no longer (fat basis) 2 temporary. *Eggs (shell-free) 0.05 *Poultry 0.01 # fenitrothion 1970b 0.001 b Apples, cherries, grapes, Date for review postponed to lettuce 0.5 b 1974 to provide longer period Red cabbage, tea (green for experiments. at harvest) 0.3 b Tomatoes 0.2 b Cocoa 0.1 b Milk products (fat basis) 0.05 b # Meat or fat of meat 0.03 b # Milk (whole) 0.002 b # Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made fensulfothion 1973b 0.0003 *Maize (grain), including Residues of fensullothlon, its kernels, of field corn and oxygen analogue, the oxygen popcorn 0.1 analogue sulfone, and the *Onions, potatoes, sulfone to be determined and rutabagas (roots), expressed as fensulfothion. tomatoes 0.1 *Peanuts (shelled), pineapple, sugarbeet 0.05 # *Bananas (whole fruit) 0.02 # *Fat of meat and edible offal of cattle, goats, and sheep 0.02 fenthion 1972b 0.0005 c Apples, peaches, cherries, Tolerances for fenthion and lettuce, fat of meat 2 c its major metabolites to be Cabbage, cauliflower, determined separately or olives, olive oil 1 c together and expressed as Grapes, oranges, peas, fenthion. meat 0.5 c Squash 0.2 c Wheat, rice, milk products (fat basis) 0.1 c Milk (whole) 0.05 c Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made fentin compounds 1965b, 0.0005 Celery 1 ) Referred to as triphenyltin in 1971b, Sugarbeet, carrots 0.2 ) see FAO/WHO 1965b. Tolerances 1973b Potatoes, celeriac 0.1 ) remarks on root crops expressed on *Cocoa beans, coffee (raw "soil free" basis. Tolerances beans), rice (in husk) 0.1 # to refer to the total amount *Peanuts and pecans of fentin compounds present, (shelled) 0.05 # expressed as fentin hydroxide. (Inorganic tin is not included in these tolerances.) ferbam 1965b, 0.025 b See dithiocarbamates. 1968b folpet 1970b 0.16 a Currants (fresh) 30 a Recommendations apply only Grapes, blueberries 25 a to parent compound. Cherries, raspberries 15 a Apples, citrus fruit 10 a Tomatoes, strawberries 5 a Cucumbers, cantaloupes (whole), watermelons (whole), onions 2 a formothion 1970b, Strawberries 0.3 Residues determined as 1973b Black currants 2 dimethoate and omethoate and expressed as dimethoate. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made heptachlor 1967b, 0.0005 Pineapple (edible portions) 0.01 Residues of heptachlor and its 1968b, Milk and milk products epoxide to be determined 1969b, (fat basis) 0.15 separately and the sum to be 1970b, Fat of meat and of poultry 0.2 expressed as heptachlor. 1971b Raw cereals, tomatoes, Certain of these practical cottonseed, soybeans, residue limits may include edible soybean oil 0.02 residues resulting from Vegetables (except carrots, applications to soil or seed. soybeans, tomatoes) 0.05 Sugarbeet 0.05 Eggs (shell-free) 0.05 Carrots 0.2 Crude soya bean oil 0.5 Citrus fruit 0.01 hexachlorobenzene 1970b (see *Fat of meat of pigs 1 a Tentative negligible daily remarks) Fat of meat of cattle, goats, intake of 0.0006 mg/kg poultry, and sheep 1 a established. (To be reviewed Eggs (shell-free) 1 a in 1973. See FAO/WHO 1970b.) Milk and milk products Fat of pigs omitted from (fat basis) 0.3 a Annex 1, FAO/WHO 1972a. Raw wheat 0.05 a Cereal products (from wheat) 0.01 a Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made hydrogen cyanide 1965c, 0.05 Raw cereals 75 Flour 6 hydrogen 1967b, Not Flour and other milled Hydrogen phosphide present phosphide 1968b, necessary cereal products, breakfast as such or derived from any 1970b, (see cereals, dried vegetables, phosphide present. Good usage 1972b remarks) spices, nuts, peanuts, practices should ensure that dried fruit, cocoa beans, residues are not detectable other dried foods 0.01 at time of consumption. Raw cereals 0.1 lead 1969b (as lead emanate) lindane 1967b, 0.0125 Vegetables 3 Referred to as gamma-BHC 1968b, Cranberries, cherries, prior to 1957. 1969b, grapes, plums, 1970b strawberries 3 *Fat of meat of cattle, pigs, and sheep 2 Beans (dried) 1 Raw cereals 0.5 Eggs (yolk) 0.2 Milk and milk products (fat basis) 0.1 Poultry (fat basis) 0.7 Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made malathion 1967b, 0.02 *Grapes 8 Recommendations for grapes 1969b, Raw cereals, nuts, dried previously omitted. 1969b, fruit 8 1971b Whole meal and flour from rye and wheat 2 Citrus fruit 4 Blackberries, raspberries, lettuce, endive, cabbage, spinach 8 Cherries, peaches, plums 6 Broccoli 5 Tomatoes, kale, turnips 3 Beans (green), apples 2 Strawberries, celery 1 Pears, blueberries, peas (in pod), cauliflower, peppers, aubergines, kohlrabi, root vegetables (except turnips), Swiss chard, collards 0.5 mancozeb 1968b, 0.025 b Potatoes 1 a Temporary tolerance applies to 1971b parent compound or to sum of all dithiocarbamates present. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made maneb 1965b, 0.025 b See dithiocarbamates. 1968b mercury compounds See organamercurials. methidathion 1973b 0.005 c *Citrus fruit 2 c *Apples, pears 0.5 c *Apricots, cherries, nectarines, peaches, plums, prunes, grapes 0.2 c *Cabbage, cauliflower, leafy vegetables 0.2 c *Beans, peas, tomatoes 0.1 c *Maize, sorghum (grain) 0.1 c *Cottonseed oil (crude) 1 c *Cottonseed 0.2 c *Hops (dried) 3 c *Tea (dry, manufactured) 0.1 c *Potatoes 0.02 # *Meat, fat, and edible offal Residues in animal products of cattle, sheep, goats, from feeding on treated forage pigs, and poultry 0.02 # and plant products. *Milk and milk products (fat basis) 0.02 # *Eggs (shell-free) 0.02 # Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made methoxychlor 1965b 0.1 methyl bromide See bromomethane. mevinphos 1965b, 0.0015 *Broccoli, Brussels sprouts, Residues of cis- and trans 1973b cabbage, cauliflower, isomers to be determined and collards 1 expressed as the sum of both. *Cherries, strawberries 1 *Apples, grapes, peaches, lettuce, spinach 0.5 *Cucumbers, tomatoes, apricots, citrus fruit, 0.2 pears *Carrots, beans, onions, peas, potatoes, turnips 0.1 *Melons 0.05 MGK 264 1968b monocrotophos 1973b 0.0003 *Apples, pears 1 c *Hops (dried) 1 *Citrus fruit 0.2 *Tomatoes 0.5 *Beans, Brussels sprouts, cabbage, cauliflower 0.2 Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made *Onions, peas, coffee (raw beans) 0.1 *Cottonseed 0.1 *Carrots, maize (grain), potatoes, turnips, sugarbeet 0.05 # *Cottonseed oil, soybeans 0.05 # *Meat and edible offal of Residues in products of animal cattle, goats, pigs, origin arising from feeding poultry, and sheep 0.02 # treated plant products. *Milk 0.002 # *Milk products 0.02 # *Eggs (shell-free) 0.02 # nabam 1965b, 0.025 b See also dithiocarbamates and 1968b zineb. omethoate 1972b 0.0005 c Apples, apricots, cherries, See also dimethoate and grapes, peaches, pears, formothion. plums 2 c organomercurials 1967b, Possible Referred to as phenylmercury 1968b figures acetate In FAO/WHO 1967b. are suggested in FAO/ WHO 1968b, p. 208. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made oxydemeton-methyl 1968b, ADI withdrawn at 1968 Meeting 1969b (see FAO/WHO 1969b). oxythioquinox 1969b See chinomethionate. paraquat 1971b, 0.002 *Rice (in husk) 10 Tolerances no longer 1973b *Olives (fresh) 1 temporary. *Rice (polished), sorghum 0.5 ADI equivalent to 0.0014 *Cottonseed, potatoes 0.2 expressed as paraquat ion. *Maize, soybeans 0.1 Residues expressed as cottonseed oil (refined) 0.05 paraquat ion. *Other vegetables 0.05 # *Milk (whole) 0.01 # parathion 1965b, 0.005 Apricots, citrus fruit, 1968b, peaches 1 1970b, Other fresh fruit 0.5 1971b Vegetables (except carrots) 0.7 parathion-methyl 1969b, 0.001 c Fruit, cole crops, cucurbits 0.2 c Cucurbits include cantaloupes, 1973b Other vegetables 1 c melons, and cucumbers. Cottonseed oil 0.05 c Temporary tolerances are for parathion-methyl plus its oxygen analogue. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made 2-phenylphenol 1970b 1 Cantaloupes (whole) 120 Residues expressed as 2- (and sodium salt) Pears 25 phenylphenol. Referred to as Carrots, peaches 20 o-phenylphenol in FAO/WHO Apples, sweet potatoes, 1969a, p. 18. plums (including fresh prunes) 15 Cantaloupes (edible portions), citrus fruit, cucumbers, peppers, pineapple, tomatoes 10 Cherries, nectarines 3 o-phenylphenol See 2-phenylphenol. phosalone 1973b 0.006 *Apples, grapes, peaches, plums 5 *Cherries, pears, beetroots 2 *Hops (dried) 2 *Citrus fruit, strawberries, broccoli, Brussels sprouts, cabbage, cucumbers, lettuce, peas, tomatoes 1 *Chestnuts and pecans (shelled), potatoes, rape seed 0.1 # Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made phosphamidon 1965b, 0.001 *Apples, pears 0.5 1967b, *Citrus fruit 0.4 Expressed as the sum of 1969b, *Other fruit, cole crops 0.2 phosphamidon and its desethyl 1972b, *Tomatoes, lettuce, derivative. 1973b cucumbers, watermelons 0.1 *Other vegetables (except root vegetables) 0.2 *Raw cereals 0.1 *Root vegetables, potatoes 0.05 # phosphine 1965c See hydrogen phosphide. piperonyl butoxide 1967b, 0.03 Raw cereals 20 a 1968b, Fresh fruit and vegetables, Peanuts omitted from Annex 1, 1973b dried fruit and vegetables 8 a FAO/WHO 1972a and from *Peanuts (whole), tree nuts, 8 a earlier tables. See FAO/WHO oil seeds 1967b. *Fish (dried) 20 Propham 1965b pyrethrins 1967b, 0.04 Raw cereals 3 a 1968b, Fresh fruit and vegetables, 1970b, dried fruit and vegetables, 1973b oil seeds, tree nuts 1 a *Fish (dried) 3 Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made quintozene 1970b 0.001 Mushrooms 10 a Peanuts (whole) 5 a Bananas (whole) 1 a Lettuce, peanuts (kernels) 0.3 a Beans (navy), potatoes 0.2 a Tomatoes 0.1 a Cottonseed 0.03 a Broccoli, cabbage 0.02 a Bananas (pulp), beans (other than navy), peppers (bell) 0.01 a 2,4,5-T 1971b thiabendazole 1971b, 0.05 Apples, pears 10 1972b, *Citrus fruit 10 1973b Bananas 3 Bananas (pulp) 0.4 thiometon 1970b thiram 1965b, 0.025 b 1968b See dithiocarbamates. toxaphene 1969b Subsequently listed as camphechlor. Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made trichlorfon 1972b 0.01 c Peppers 1 c Bananas, peaches, Brussels sprouts, cauliflower, kale, sweet corn (kernels and cobs), celery, beet, wheat 0.2 c Apples, cherries, oranges, strawberries, artichokes, beans (blackeyed, green, and lima), cabbage, cowpeas, mustard greens, pumpkins, tomatoes, turnips 0.1 c Barley, maize 0.1 c Cottonseed, linseed, rape seed, safflower seed, soybeans, peanuts (shelled) 0.1 c Meat, fat, and edible offal of cattle and pigs 0.1 c Milk (whole) 0.05 c Sugarbeet 0.05 e trichloroethylene 1969b trichloronat 1972b Annex 1 (Cont'd.) Maximum Residue limits acceptable daily Pesticide Ref.1 intake Commodity Practical Guideline Remarks (mg/kg Tolerances limits2 levels3 body (mg/kg) (mg/kg) (mg/kg) weight) Blank spaces indicate no recommendations made tricyclohexyl 1971b 0.0075 b Apples, pears 2 b Expressed as the parent hydroxystannate compound. tricyclohexyltin See tricyclohexyl hydroxide hydroxystannate. triphenyltin See fentin compounds. zineb 1965b, 0.025 b (Including zineb derived from 1968b nabam plus zinc sulfate.) ziram 1965b, 0.025 b See also dithiocarbamates. 1968b Indicates additions or irodifications made by the 1972 Joint Meeting. 1 References are to FAO/WHO publications (see list of references). Dates of publication refer to the first complete or completely revised monograph or to important mentions of the compound in a report. Where a monograph has been completely revised mention is not necessarily made of any earlier ones. Where the only date given is 1973, the compound was considered at the 1972 Joint Meeting for the first time. 2 Unless otherwise indicated, the tolerances and practical limits should apply as soon as practicable after harvest to the raw agricultural products moving in commerce and prior to processing. For commodities entering international trade, tolerances are applicable, unless otherwise indicated, at the point of entry into a country or as soon as practicable thereafter. All levels refer to contents or samples representative of individual consignments or lots. Annex 1 (Cont'd.) 3 Guideline levels are included to assist administering authorities, even though ADis have not been established for the individual products, or temporary ADIs established at an earlier date have been withdrawn. The levels recommended are those that need not be exceeded if good practices are followed. With regard to fumigants, they are intended to be applied at one of the stages indicated by f, g, or h in the knowledge that, when so applied, residues of unchanged fumigants in foods as offered for consumption would not exceed an amount close to the limit of determination by present analytical methods. # Level at or about the limit of determination. a Temporary: results of work to be made available not later than 30 June 1973. b Temporary: results of work to be made available not later than 30 June 1974. c Temporary: results of work to be made available not later than 30 June 1975. d Temporary: results of work to be made available not later than 30 June 1976. e Temporary: results of work to be made available not later than 30 June 1977. f To apply at point of entry into a country and, in the case of cereal for milling, if product has been freely exposed to air for a period of at least 24 hours after fumigation and before sampling. g To apply to milled cereal products to be subjected to baking or cooking. h To apply at point of retail sale or when offered for consumption. ANNEX 2 REFERENCES FAO/WHO. (1964) Evaluation of the toxicity of Pesticide residues in food; report of a Joint Meeting of the FAO Committee on Pesticides in Agriculture and the WHO Expert Committee on Pesticide Residues. FAO Meeting Report, No. PL/1963/13; WHO/Food Add./23 (1964) FAO/WHO. (1965a) Evaluation of the toxicity of pesticide residues in food; report of the Second Joint Meeting of the FAO Committee on Pesticides in Agriculture and the WHO Expert Committee on Pesticide Residues, FAO Meeting Report, No. PL/1965/10; WHO/Food Add./26.65 FAO/WHO. (1965b) Evaluation of the toxicity of pesticide residues in food. FAO Meeting Report, No. PL/1965/10/1; WHO/Food Add./27.65 FAO/WHO. (1965c) Evaluation of the hazards to consumers resulting from the use of fumigants in the protection of food. FAO Meeting Report, No. PL:1965/10/2; WHO/Food Add./28.65 FAO/WHO. (1967a) Pesticide residues in food; joint report of the FAO Working Party on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 73; Wld Hlth Org. techn. Rep. Ser., No. 370 FAO/WHO. (1967b) Evaluation of some pesticide residues in food. FAO, PL:CP/15; WHO/Food Add./67.32 FAO/WHO. (1968a) Pesticide residues; report of the 1967 Joint Meeting of the FAO Working Party and the WHO Expert Committee. FAO Meeting Report, No. PL:1967/M/11; Wld Hlth Org. techn. Rep. Ser., No. 391 FAO/WHO. (1968b) 1967 evaluations of some pesticide residues in food. FAO/PL:1967/M/11/1; WHO/Food Add./68.30 FAO/WHO. (1969a) Pesticide residues in food; report of the 1968 Joint Meeting of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 78; Wld Hlth Org. techn. Rep. Ser., No. 417 FAO/WHO. (1969b) 1969 evaluations of some pesticide residues in food. FAO/PL:1968/M/9/1; WHO/Food Add./69.35 FAO/WHO. (1970a) Pesticide residues in food; report of the 1969 Joint Meeting of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Group on Pesticide Residues. FAO Agricultural Studies, No. 84; Wld Hlth Org. techn. Rep. Ser., No. 458 FAO/WHO. (1970b) 1969 evaluations of some pesticide residues in food. FAO/PL:1969/M/17/1; WHO/Food Add./70.38 FAO/WHO. (1971a) Pesticide residues in food; report of the 1970 Joint Meeting of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Group on Pesticide Residues. FAO Agricultural Studies, No. 87; Wld Hlth Org. techn. Rep. Ser., No. 474 FAO/WHO. (1971b) 1970 evaluations of some pesticide residues in food. FAO/AGP/1970/M/12/1; WHO/Food Add./71.42 FAO/WHO. (1972a) Pesticide residues in food; report of the 1971 Joint Meeting of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 88; Wld Hlth Org. techn. Rep. Ser., No. 502 FAO/WHO. (1972b) 1971 evaluations of some pesticide residues in food, FAO/AGP/1971/M/9/1; WHO Pesticide Residues Series, No. 1 FAO/WHO. (1972c) Report of the Sixth Session of the Codex Committee on Pesticide Residues. Alinorm 73/24 FAO/WHO. (1972d) Evaluation of certain food additives and the contaminants mercury, lead, and cadmium. Sixteenth report of the Joint FAO/WHO Expert Committee on Food Additives. FAO Nutrition Meetings Report Series, No. 51; Wld Hlth Org. techn. Rep. Ser., No. 505 FAO/WHO. (1973b) 1972 evaluations of some pesticide residues in food. FAO/AGP/1972/M/9/1; WHO Pesticide Residues Series, No. 2 (in press) WHO. (1967) Procedures for investigating intentional and unintentional food additives; report of a WHO Scientific Group. Wld Hlth Org. techn. Rep. Ser., No. 348
See Also: Toxicological Abbreviations