PESTICIDE RESIDUES IN FOOD - 1980 Sponsored jointly by FAO and WHO EVALUATIONS 1980 Joint meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues Rome, 6-15 October 1980 ANNEX I ACCEPTABLE DAILY INTAKES, RESIDUE LIMITS AND GUIDELINE LEVELS RECOMMENDED AT THE 1980 MEETING These figures are additional to, or amend, those recorded in Annexes of the reports of earlier meetings. Limits recommended at meetings from 1965 - 1977 inclusive are summarized in document FAO/WHO 1978c. This Table includes maximum acceptable daily intakes (ADIs), maximum residue limits (MRLs), extraneous residue limits (ERLs) and guideline levels (GLs). These terms are defined in Annex 3 of the report of the 1975 meeting. Some ADIs and MRLs are temporary: in these cases the year in which further data are required is specified in parenthesis. ERLs are identified by the symbol (E) after the limit. Part 1 lists ADIs, MRLs and ERLs. Part 2 lists GLs. New, as distinct from amended, recommendations are identified by the symbol * before the commodity or before the ADI. Residue levels at or about the limit of determination are followed by the symbol **. Certain corrections of previous publications are included. PART 1 - ACCEPTABLE DAILY INTAKES (ADIs) AND MAXIMUM RESIDUE LIMITS (MRLs) Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) amitraz *0.0005 *cherries 0.5 Temporary MRLs are (1984) *cottonseed 0.5 for the sum of *cucumbers 0.5 amitraz, calculated *peaches 0.5 as N-(2,4-dimethyl- *pome fruit 0.5 phenyl)-N-methyl- *oranges 0.5 formamidine and N- (2,4-dimethylphenyl)- *carcase meat of cattle 0.05 N-methylformamidine. *carcase meat of pigs 0.05 *carcase meat of sheep 0.2 The limit for olive oil *cattle meat byproducts 0.2 is temporary until *sheep meat byproducts 0.2 requirement 4 of para. *milk 0.01** 4.1 of the report is met irrespective of the *olive oil 0.05 status of the ADI *cottonseed oil 0.05 sec-butylamine 0.1 dried citrus pulp 100 1975,1977,1978,1979 captan 0.1 cherries 50 1965,1969,1973,1974, potatoes 20 1977,1978 carbofuran 0.01 Temporary ADI converted 1976,1979 to ADI at higher level. Temporary MRLs replaced by MRLs. chlordimeform 0.0001 Temporary ADI extended 1971,1975,1977,1978, (1985) at same level. 1979 PART 1 - CONTINUED... Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) coumaphos ADI withdrawn (see Part II) cyanofenphos 0.001 Temporary ADI 1975,1978 (1982) extended at lower level. cyhexatin 0.008 Temporary ADI 1970,1973,1974, (1981) extended at same 1977,1978 level. 2,4-D 0.3 barley 0.5 Recommended MRLs 1970,1971,1974, oats 0.5 replace previous 1975 rye 0.5 recommendation of wheat 0.5 0.2 mg/kg for raw other cereal grains 0.2 grain. DDT 0.005 Conditional ADI 1965,1966,1967, (condi- extended at same 1968,1969,1979 tional) level. dithiocarbamates, 0.02 apples 3 Temporary ADI for dimethyl (ADI is for bananas 1 thiram extended at ferbam, ziram the sum of bananas (pulp) 0.1 same level. MRLs ferbam, and beans 0.5 are temporary until ziram) carrots 0.5 requirements 3 and 4 celery 5 of para. 4.14 of the thiram 0.005 cherries 1 report are met. 1965,1967,1970, (1982) cucumbers 0.5 Limits are for 1974,1977 currants 5 residues determined endive 1 and expressed as CS2 grapes 5 lettuce 1 melons 1 peaches 3 PART 1 - CONTINUED... Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) thiram (cont'd) pears 3 plums 1 potatoes 0.1 strawberries 3 tomatoes 3 wheat 0.2 dithiocarbamates, 0.05 apples 3 Temporary ADI converted ethylenebis (not more bananas 1 to ADI at higher level. (mancozeb, maneb and than 0.002 bananas (pulp) 0.1 MRLs are temporary zineb, including present as beans 0.5 temporary until zineb derived from ethylene- carrots 0.5 requirements 1,2 and nabam plus zinc thiourea celery 5 4 of para. 4.14 of the sulphate) (ETU). ADI cherries 1 report are met. Limits 1965,1967,1970, is for the cucumbers 0.5 are for residues 1974,1977 sum of currants, black & red 5 determined and maneb, endive 1 expressed as CS2. mancozeb grapes 5 Guideline levels and zineb.) lettuce 1 for ethylenethiourea melons 1 (ETU) are listed peaches 3 in Part 2. pears 3 plums 1 potatoes 0.1 strawberries 3 tomatoes 3 wheat 0.2 dithiocarbamates, 0.005 propylenebis (1982) apples 3 Temporary ADI extended (propineb) bananas 1 at same level. MRLs 1977 bananas (pulp) 0.1 are temporary until beans 0.5 requirements 3 and 4 carrots 0.5 of para. 4.14 of the celery 5 report are met. PART 1 - CONTINUED... Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) propineb (cont'd) cherries 1 Limits are for cucumbers 0.5 residues determined currants, black red 5 and expressed as CS2 endive 1 grapes 5 lettuce 1 melons 1 peaches 3 pears 3 plums 1 potatoes 0.1 strawberries 3 tomatoes 3 wheat 0.2 ethiofencarb 0.1 Temporary ADI 1977,1978 (1982) extended at same level. etrimfos *0.003 *barley 10 Temporary MRLs are (1982) *maize 10 for etrimfos. *rapeseed 10 Metabolites are not *wheat 10 included. *carcase meat of cattle O.01** Limits are temporary *cattle meat byproducts 0.01** until requirements *milk 0.01** 2 and 3 of para. 4.16 of the report are met, *rapeseed oil (refined) 0.5 irrespective of the *wheat bran (unproceooed) 20 status of the ADI. *wheat flour (white) 2 *wheat flour (wholemeal) 10 PART 1 - CONTINUED... Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) fenamiphos 0.0006 citrus fruit Temporary MRL for tomatoes 1974,1977,1978 (except oranges) MRL replaces temporary withdrawn MRL at same level. *kiwi fruit 0.05** tomatoes 0.2 fenthion 0.001 Temporary ADI converted 1971,1975,1977,1978, to ADI at higher level. 1979 Temporary MRLs replaced by MRLs. ferbam 0.02 See dithiocarbamates dimethyl. guazatine 0.03 citrus fruits 5 MRL for citrus fruits 1978 *melons 5 replaces temporary MRL at same level. MRLs are for guazatine. Metabolites are not included. imazalil 0.01 Temporary ADI extended 1977 (1984) at same level. iprodione 0.3 *kiwi fruit 5 MRL is for iprodione. 1977 Metabolites are not included. PART 1 - CONTINUED... Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) maleic hydrazide 1 onions 15 As a temporary ADI 1976,1977 (sodium potatoes 50 has been allocated, or previous GLs for potassium onions and potatoes (salt) are replaced by (1984) temporary MRLs. GLs for tobacco leaf and tobacco product remain as such. mancozeb 0.05 See dithiocarbamates, ethylenebis. maneb 0.05 See dithiocarbamates, ethylenebis. mecarbam *0.001 *oranges 2 Temporary MRL is for (1983) mecarbam. Metabolites are not included. methacrifos *0.0003 *beans (dry) 5 Temporary MRLs are (1983) *cereal grains 10 for the methacrifos. *cocoa beans 10 Metabolites are not *peas (dry) 5 included. *peanuts 1 *peanuts (with shell) 10 *milk 0.01** *poultry meats 0.01** *eggs 0.01** *wheat bran (unprocessed) 20 *wheat flour(white) 2 *wheat flour (wholemeal) 10 PART 1 - CONTINUED... Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) omethoate 0.0005 Temporary ADI extended 1971,1975,1978 (1981) at same level. oxamyl *0.01 (1983) *apples 2 Temporary MRLs are *bananas 0.05** for the sum of *beans, kidney (1983)3 oxamyl and its oxime *beans, kidney (dry) (1983)0.05** calculated as oxamyl. *beans, Lima (1983)3 Limits proceeded by *beets 0.1 (1983) are temporary *carrots 0.1 until requirements *celery 3 3, 4 and 5 of para. *citrus 3 4.26 are met, *cottonseed (1983)0.2 irrespective of the *cucumber 2 status of the ADI. *maize (1983)0.05** *melon 2 *peanuts (1983)0.1 *peanut fodder (1983)2 *peppers 3 *pineapple (1983)1 *potatoes 0.1 *sugarbeets 0.1 *summer squash 2 *soybeans (dry) (1983)0.05** *sweet potatoes (1983)0.1 *tomatoes 2 *watermelons 2 parathion-methyl 0.001 other vegetables Temporary Temporary ADI extended 1965,1968,1972, (1982) MRL at same level. 1975,1978,1979 withdrawn PART 1 - CONTINUED... Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) permethrin 0.03 *cereal grains 2 MRLs are for 1979 (1981) permethrin (sum of isomers). Metabolites are excluded. *alfalfa fodder 100 ) *apple pomace 50 ) on a dry weight basis *maize fodder & straw 100 ) *soyboan fodder 50 ) *carcase meat of catt le 1 ) *carcase meat of pig. 1 ) MRLs apply to carcase *carcase meat of sheep 1 ) fat. *poultry meats 0.1 ) 0.03 *cattle meat byproducts 0.1 (1981) *pig meat byproducts 0.1 *sheep meat byproducts 0.1 *milk 0.1 *eggs 0.1 *wheat bran 10 *wheat flour (white) 0.5 *wheat flour (wholemeal) 2 phenothrin *0.2 *wheat bran 15 As a temporary ADI (1984) *cereal grains 5 has been allocated, previous GLs are replaced by temporary MRLs. phenthoate *0.001 *citrus fruits 1 MRLs are for (1984) phenthoate. *carcase meat of cattle 0.05** Metabolites are *milk 0.01** not included. *eggs 0.05** PART 1 - CONTINUED... Pesticide and ADI dates of previous (mg/kg Recommended evaluations body Commodity MRL Remarks (see Annex II) weight) (mg/kg) propineb 0.005 Temporary ADI extended at same level. See dithio- carbamates, propylenebis. propargite 0.08 raisins MRL Temporary ADI extended 1977,1978,1979 (1982) Withdrawn at same level. Residues in raisins are covered by the MRL of 10 mg/kg in grapes. thiram 0.005 See dithiocarbamates, (1981) dimethyl. zineb 0.05 See dithiocarbamates, ethylenebis. ziram 0.02 See dithiocarbamates, dimethyl. PART 2 - GUIDELINE LEVELS (GLs) NO ADIs Pesticide and dates of previous Commodity GL Remarks evaluations (mg/kg) (see Annex II) coumaphos carcase meat of cattle 1 Temporary ADI withdrawn, 1968,1972,1975, GLs replace temporary 1978 MRLs at same levels. They are for the sum of coumaphos and its oxygen analouge. carcase meat of cattle 1 ) carcase meat of goats 0.5 ) GLs apply to carcase carcase meat of pigs 0.5 ) fat. carcase meat of sheep 0.5 ) poultry meats 1 ) eggs 0.05 milk 0.02 milk products 0.5 (fat basis) *deltamethrin *artichokes 0.05 GLs are for deltamethrin. (decamethrin) *assorted fruits - edible peel 0.1 Metabolites are not *bananas 0.05 included. *brassica leafy vegetables 0.05 *bulb vegetables 0.1 *cereal grains 1 *clementines 0.05 *cocoa beans 0.05 *Coffee beans 2 *fruiting vegetables - edible peel 0.05 *grapes 0.05 *leafy vegetables 0.2 *legume animal feeds 0.5 dry weight basis *legume oilseeds 0.01 *legume vegetables 0.1 *melons 0.01 *mushrooms 0.01 *oilseeds 0.1 Pesticide and dates of previous Commodity GL Remarks evaluations (mg/kg) (see Annex II) deltamethrin *oranges 0.05 (cont'd) *pineapples 0.01 *pome fruits 0.1 *root and tuber vegetables 0.01 *stone fruits 0.05 *strawberries 0.05 *tea 10 *wheat bran (unprocessed) 2 *wheat flour (white) 0.5 ethylenethiourea apples 0.02 See also 1974 banana (pulp) 0.01** dithiocarbamates, beans 0.1 ethylenebis carrots 0.01** celery 0.01** lettuce 0.01** maize 0.01** pears 0.02 potatoes 0.01** sweet corn 0.01** tomatoes 0.05 ANNEX II PREVIOUS FAO AND WHO DOCUMENTATION FAO/WHO (1958) - Procedures for the testing of intentional food additives to establish their safety for use. 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See Also: Toxicological Abbreviations