PESTICIDE RESIDUES IN FOOD - 1983 Sponsored jointly by FAO and WHO EVALUATIONS 1983 Data and recommendations of the joint meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues Geneva, 5 - 14 December 1983 Food and Agriculture Organization of the United Nations Rome 1985 ANNEX I ACCEPTABLE DAILY INTAKES, MAXIMUM RESIDUE LIMITS AND GUIDELINE LEVELS PROPOSED AT THE 1983 MEETING These figures are additional to, or amend, those recorded in Annexes of the reports of earlier meetings. Limits recommended at meetings from 1965-1977 inclusive are summarized in document FAO/WHO 1978c. This table includes maximum acceptable daily intakes (ADIs), maximum residue limits (MRLs) and guideline levels (GLs). These terms are defined in Annex 3 of the Report of the 1975 Meeting. Part I lists ADIs and MRLs. Some ADIs and MRLs are temporary; in these cases the year in which further data are required is specified in parentheses below the ADI. Part 2 lists GLs. New, as distinct from amended, recommendations are identified by the symbol * before the commodity or before the ADI. Residue levels at or about the limit of determination are followed by the symbol **. Amended recommendations are followed by the previous recommendation in parentheses. PART 1. - ACCEPTABLE DAILY INTAKES (ADIs) and MAXIMUM RESIDUE LIMITS (MRLs) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) amitraz 0.0005 carcase meat 0.1 (0.2) The previously 1980 (1984) of sheep recommended temporary MRL of 0.5 mg/kg in cucumbers is reaffirmed. MRLs are for the sum of amitraz, calculated as N-(2,4-dimethylphenyl)- N-methylformamidine, and N-(2,4-dimethylphenyl)- N-methylformamidine. azocyclotin 0.003 beans 0.2 (0.5) MRLs are for the sum of 1979, 1981, azocyclotin, cyhexatin 1982 and dicyclohexyltin oxide, expressed as cyhexatin. MRLs for azocyclotin and cyhexatin are not additive (see paras 4.3 and 4.15). benomyl *0.02 ADIs have been 1973, 1975, estimated for benomyl 1978 and carbendazim. MRLs for carbendazim apply also to benomyl. bitertanol *0.005 Residue data to be (1987) evaluated in 1984. PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) bromide ion 1 *celery 300 1968, 1969, *cucumbers 50 1971, 1979, *tomatoes 75 1981 carbendazim *0.01 apricots 10 (5) As an ADI has been 1973, 1976, *asparagus1 0.1** estimated, previously 1977, 1978 *blueberries 5 recorded GLs are *chestnuts1 0.2 replaced by MRLs. *eggplant 0.5 Only new and amended grapes 10 (5) limits are listed here. *hops, dry 50 They are for carbendazim. melons 2 (0.5) Metabolites are not *oats 0.5 included. *onions 2 *peppers 5 1 MRLs based on data *pineapples1 20 from treatment with *rutabagas 0.1** benomyl. *soybeans 0.2 *sweet potatoes1 1 *taro1 0.1** bean fodder 50 (30 for bean vines) peanut hay 5 (2) peanut hulls1 1 (0.2) rice straw 15 (2) *soybean hay 0.1** sugarbeet tops 10 (5) wheat straw1 5 (2) PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) carbophenothion 0.0005 The definition of the 1972, 1976, residue in commodities of 1977, 1979, plant origin is changed, 1980 and is now identical to that in commodities of animal origin: sum of carbophenothion, its sulphoxide and its sulphone, expressed as carbophenothion. chlorothalonil 0.005 lima beans 0.5 (0.5 Temporary ADI extended at 1974, 1977, (1985) (without pod) for same level. The definition 1978, 1979, lima of the residue is changed 1981 beans) to chlorothalonil. Metabolites are not included. The temporary MRL for grapes (5 mg/kg) remains temporary, irrespective of the status of the ADI, pending further residues data (see para 4.11). chlorpyrifos 0.01 *dried vine 2 MRLs are for chlorpyrifos. 1972, 1974, fruit Metabolites are not 1975, 1977, included. 1981, 1982 PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) cyanofenphos No ADI Temporary ADI withdrawn. 1975, 1978, Temporary MRLs replaced 1980, 1982 by Gls. cyhexatin 0.008 beans 0.2 (0.5) MRLs are for the sum of 1970, 1973, *Kiwi fruit 5 cyhexatin and dicyclohexyltin 1974, 1975, peaches 5 (2) oxide, expressed 1977, 1978, as cyhexatin. 1980, 1981, MRLs for cyhexatin and 1982 azocyclotin are not additive (see paras 4.3 and 4.15). dichlofluanid 0.3 Temporary ADI replaced 1969, 1974, by ADI at same level. 1977, 1979, Temporary MRLs replaced 1981, 1982 by MRLs. diflubenzuron 0.004 mushrooms 0.1 (0.2) Temporary MRLs are for 1981 (1984) plums MRL (1) diflubenzuron. withdrawn Metabolites are not included. ethiofencarb 0.1 beans 2 (0.5) MRLs are for the sum of 1977, 1978, (with pod) ethiofencarb, its 1981, 1982 sulphoxide and its sulphone. PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) ethion 0.001 The definition of the 1968, 1969, (1985) residue is changed to 1970, 1972, ethion. Metabolites 1975, 1982 are not included. fenchlorphos 0.01 The definition of the 1968, 1972 residue in commodities of plant origin is changed to fenchlorphos and is now identical to that in commodities of animal origin. fenitrothion 0.001 oranges 2 (0.2) The definition of the 1969, 1974, (1984) *mandarins 2 residue is changed to 1976, 1977, fenitrothion. Metabolites 1979, 1982 are not included. The MRLs for oranges and mandarins remain temporary, irrespective of the status of the ADI, pending the receipt of information on GAP. PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) mecarbam 0.001 *citrus fruit 2 Temporary ADI extended at 1980 (1985) same level. Temporary MRL replaces the temporary MRL for oranges at the same level. It is for mecarbam. Metabolites are not included. methiocarb 0.001 *Chinese radishes 5 Previously estimated ADI 1981 citrus fruit 0.05**(0.02) confirmed. MRLs are for *sorghum 5 the sum of methiocarb, strawberries 0.05** (0.02**) its sulphoxide and its sugarbeets 0.05** (0.02) sulphone. apples MRL withdrawn (10) MRLs withdrawn pending blueberries " " (25) toxicological re- cherries " " (10) evaluation by JMPR (see currants (red) " " (5) report, para. 4.33). grapes " " (5) peaches " " (15) *eggs 0.05**1 1 MRLs do not allow for *meat 0.05**1 possible feeding of straw *milk 0.05**1 and similar fodder from *poultry 0.05**1 crops sprayed with methiocarb to repel birds. oxamyl 0.01 bananas 0.2 (0.05**) Temporary ADI extended at 1980 (1984,FAO) *coffee beans 0.1 same level. Previously (1985,WHO) cucumbers 0.5 (2) recommended MRLs for *onions 0.05** maize and soybeans were soybeans (dry) 0.1 (0.05**) temporary, irrespective PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) *sugarcane 0.05** of the status of the ADI, pending the receipt of data on residues and use patterns, which have now been supplied. Temporary MRLs are for the sum of oxamyl and its oxime, expressed as oxamyl. permethrin 0.05 beans 1 (0.5 for MRLs are for permethrin 1979, 1980, (with pod) beans, whole (sum of isomers). 1981, 1982 green) Metabolites are not *legume 0.1 included. oilseeds *sorghum 20 (on a dry fodder weight basis) 2-phenylphenol 0.02 ADI replaced by 1969, 1975 (1985) temporary ADI at lower level. MRLs replaced by temporary MRLs. phorate 0.0002 Temporary ADI extended 1977, 1982 (1985) at same level. PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) phoxim 0.0005 *beans 0.05** MRLs are for phoxim. 1982 (1984) *cauliflower 0.05** Metabolites are not *cereal grains 0.05** included. *cottonseed 0.05** *lettuce 0.1 *potatoes 0.05** *tomatoes 0.2 *carcase meat 0.2 (in the of cattle carcase fat) *carcase meat 1 (in the of sheep carcase fat) pirimiphos-methyl *0.01 The definition of the residue in commodities 1974, 1976, of plant origin is 1977, 1979 changed to pirimiphos-methyl and is now identical to that in commodities of animal origin. prochloraz *0.01 *barley 0.05** *citrus fruit 5 *mushrooms 2 MRLs are for prochloraz. *oats 0.05** Metabolites are not *rye 0.05** included. The MRL for *wheat 0.05** citrus is temporary l until information on PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) *barley straw 0.2 GAP is provided. *oat straw 0.2 *rye straw 0.2 *wheat straw 0.2 *avocados 5 MRLs are for the sum of *bananas 5 prochloraz and its free *mangos 2 and conjugated metabolites *papayas 1 containing the 2,4,6-tri= *rapeseed 0.5 chlorophenol moiety. *stone fruit 1 They are all temporary until information on GAP and/or trials data in which residues are determined as prochloraz have been provided. propineb 0.005 Temporary ADI extended at 1977, 1980 (1985) same level. propoxur 0.02 cereal grains 0.1 (0.5) The definition of the 1973, 1977, residue is changed to 1981 fodders and 1 (5) propoxur. Metabolites straws (green) are not included. legume animal 1 (5) The amended MRLs have feeds (green) been lowered to accommodate the revised residue definition. PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) tecnazene 0.01 Temporary ADI replaced 1974, 1978, by ADI at same level. 1981 Temporary MRLs replaced by MRLs. thiram 0.005 Temporary ADI extended 1965, 1967, (1985) at same level. 1970, 1974, 1977, 1980 triadimefon 0.01 *pineapple 2 Temporary ADI extended 1979, 1981 (1985) *pome fruit 0.5 at same level. MRLs wheat 0.2 (0.1**) are for the sum of triadimefon and *fodder beet 0.1** "triadimenol". *fodder beet 0.1** leaves *poultry meat 0.1** triazophos 0.0002 *bananas 2 Temporary MRLs are for 1982 (1986) *Brussels sprouts 0.1 triazophos. Metabolites *cabbage 0.1 are not included. *carrots 0.1 *cereal grains 0.5** *citrus fruit 2 *coffee beans 0.05** *cottonseed 0.1 *onions 0.1 PART 1. (continued) Pesticide and ADI Commodity Recommended Remarks year of (mg/kg MRL previous body (mg/kg) evaluations weight) *pome fruit 0.2 *peas 0.1 *potatoes 0.5** *sugarbeet 0,05** PART 2. - GUIDELINE LEVELS (GLs) (NO ACCEPTABLE DAILY INTAKES) Pesticide and Commodity Remarks year of GL previous (mg/kg) evaluations azinphos-ethyl The definition of the residue 1973 is changed to azinphos-ethyl. Metabolites are not included. butocarboxim *apples 2 GLs are for the sum of *beans (with pod) 5 butocarboxim, its sulphoxide *cabbage 1 and its sulphone, expressed *citrus fruit 2 as butocarboxim. *lettuce 2 *radishes 2 The GL for lettuce is based *stone fruit 5 exclusively on data from *sugarbeet 0.1 trials on outdoor crops. *tomatoes 1 *sugarbeet leaves 5 nitrofen *wheat 0.01** GLs are for nitrofen. *wheat straw 0.05 Metabolites are not included. ANNEX II PREVIOUS FAO AND WHO DOCUMENTS FAO/WHO. Principles governing consumer safety in relation to 1962 pesticide residues. Report of a meeting of a WHO Expert Committee on Pesticide Residues held jointly with the FAO Panel of Experts on the Use of Pesticides in Agriculture. FAO Plant Production and Protection Division Report. No.PL:1961/11: WHO Technical Report Series, No.240. FAO/WHO. Evaluation of the toxicity of pesticide residues in 1964 food; report of a Joint Meeting of the FAO Committee on Pesticides in Agriculture and the WHO Expert Committee on Pesticide Residues. FAO Meeting Report, No.PL:1963/13: WHO/Food Add./23 (1964). FAO/WHO. Evaluation of the toxicity of pesticide residues in food. 1965a Report of the Second Joint Meeting of the FAO Committee on Pesticides in Agriculture and the WHO Expert Committee on Pesticide Residues. FAO Meeting Report, No. PL:1965/10: WHO Food Add./26.65. FAO/WHO. Evaluation of the toxicity of pesticide residues in food. 1965b FAO Meeting Report, No.PL:1965/10/1: WHO Food Add./27.65. FAO/WHO. Evaluation of the hazards to consumers resulting from the 1965c use of fumigants in the protection of food. FAO Meeting Report, No.PL:1965/10/2: WHO Food Add./28.65. FAO/WHO. Pesticide residues in food. Joint report of the FAO Working 1967a Party on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 73: WHO Technical Report Series, No. 370. FAO/WHO. Evaluation of some pesticide residues in food. FAO:PL/CP/15: 1967b WHO Food Add./67.32. FAO/WHO. Pesticide residues. Report of the 1967 Joint Meeting of the 1968a FAO Working Party and the WHO Expert Committee. FAO Meeting Report, No.PL:1967/M/11:WHO Technical Report Series, No. 391. FAO/WHO. 1967 evaluation of some pesticide residues in food. FAO 1968b PL:1967/M/11/1: WHO Food Add./68.30. FAO/WHO. Pesticide residues in food. Report of the 1968 Joint Meeting 1969a of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 78: WHO Technical Report Series, No. 417. FAO/WHO. 1968 evaluation of some pesticide residues in food. FAO 1969b PL:1968/M/9/1: WHO Food Add./69.35. FAO/WHO. Pesticide residues in food. Report of the 1969 Joint Meeting 1970a of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Group on Pesticide Residues. FAO Agricultural Studies, No. 84: WHO Technical Report Series, No. 458. FAO/WHO. 1969 evaluations of some pesticide residues in food. FAO 1970b PL:1969/M/17: WHO Food Aff./70.38. FAO/WHO. Pesticide residues in food. Report of the 1970 Joint Meeting 1971a of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Group on Pesticide Residues. FAO Agricultural Studies, No. 87: WHO Technical Report Series, No. 474. FAO/WHO. 1970 evaluations of some Pesticide residues in food. 1971b AGP 1970/M/12/1: WHO Food Add./71.42. FAO/WHO. Pesticide residues in food. Report of the 1971 Joint Meeting 1972a of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 88: WHO Technical Report Series, No. 502. FAO/WHO. 1971 evaluations of some pesticide residues in food. AGP: 1972b 1971/M/9/1: WHO Pesticide Residues Series, No. 1. FAO/WHO. Pesticide residues in food. Report of the 1972 Joint Meeting 1973a of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 90: WHO Technical Report Series, No. 525. FAO/WHO. 1972 evaluations of some pesticide residues in food. AGP: 1973b 1972/M/9/1: WHO Pesticide Residues Series, No. 2. FAO/WHO. Pesticide residues in food. Report of the 1973 Joint Meeting 1974a of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 92: WHO Technical Report Series, No. 545. FAO/WHO. 1973 evaluations of some pesticide residues in food. AGP: 1974b 1973/M/9/1: WHO Pesticide Residues Series, No. 3. FAO/WHO. Pesticide residues in food. Report of the 1974 Joint Meeting 1975a of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Agricultural Studies, No. 97: WHO Technical Report Series, No. 574. FAO/WHO. 1974 evaluations of some pesticide residues in food. AGP: 1975b 1974/M/11: WHO Pesticide Residues Series, No. 4. FAO/WHO. Pesticide residues in food. Report of the 1975 Joint Meeting 1976 of the FAO Working Party of Experts on Pesticide Residues and the WHO Expert Committee on Pesticide Residues. FAO Plant Production and Protection Series, No. 1: WHO Technical Report Series, No. 592. FAO/WHO. Pesticide residues in food. Report of the 1976 Joint Meeting 1977a of the FAO Panel of Experts on Pesticide Residues and the Environment and the WHO Expert Group on Pesticide Residues. FAO Food and Nutrition Series, No. 9. FAO Plant Production and Protection Series, No. 8: WHO Technical Report Series, No. 612. FAO/WHO. 1976 evaluations of some pesticide residues in food. AGP: 1977b 1976/M/14. FAO/WHO. Pesticide residues in food. Report of the 1977 Joint Meeting 1978a of the FAO Panel of Experts on Pesticide Residues and the Environment and the WHO Expert Group on Pesticide Residues. FAO Plant Production and Protection Paper 10 Rev. FAO/WHO. 1977 evaluations of some pesticide residues in food. FAO 1978b Plant Production and Protection Paper 10 Sup. FAO/WHO. Pesticide residues in food. Report of the 1978 Joint Meeting 1979a of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues. FAO Plant Production and Protection Paper 15. FAO/WHO. 1978 evaluations of some pesticide residues in food. FAO 1979b Plant Production and Protection Paper 15 Sup. FAO/WHO. Pesticide residues in food. Report of the 1979 Joint Meeting 1980a of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues. FAO Plant Production and Protection Paper 20. FAO/WHO. 1979 evaluations of some pesticide residues in food. FAO 1980b Plant Production and Protection Paper 20 Sup. FAO/WHO. Pesticide residues in food. Report of the 1980 Joint Meeting 1981a of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues. FAO Plant Production and Protection Paper 26. FAO/WHO. 1980 evaluations of some pesticide residues in food. FAO 1981b Plant Production and Protection Paper 26 Sup. FAO/WHO. Pesticide residues in food. Report of the 1981 Joint Meeting 1982a of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues. FAO Plant Production and Protection Paper 37. FAO/WHO. 1981 evaluations of some pesticide residues in food. FAO 1982b Plant Production and Protection Paper 42. FAO/WHO. Pesticide residues in food. Report of the 1982 Joint Meeting 1983a of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues. FAO Plant Production and Protection Paper 46. FAO/WHO. 1982 evaluations of some pesticide residues in food. FAO 1983b Plant Production and Protection Paper 49. FAO/WHO. Pesticide residues in food. Report of the 1983 Joint Meeting 1984a of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues. FAO Plant Production and Protection Paper 56. FAO/WHO. 1983 evaluations of some pesticide residues in food. FAO 1984b Plant Production and Protection Paper
See Also: Toxicological Abbreviations