ANNEX II ACCEPTABLE DAILY INTAKES AND RESIDUE LIMITS PROPOSED AT THE 1989 MEETING These figures are additional to, or amend, those recorded in Annexes of the reports of earlier meetings. Limits recommended at meetings from 1965 to 1977 inclusive are summarized in document FAO/WHO 1978c. This table includes maximum acceptable daily intakes (ADIs) and maximum residue limits (MRLs). These terms are defined in Annex III of the report of the 1975 meeting. Some ADIs are temporary: this is indicated by the year in which re-evaluation is scheduled in parenthesis below the ADI. Proposed MRLs may be followed by the qualifications listed below, which have the meanings shown. * : At or about the limit of determination. E : Extraneous Residue Limit (ERL). F (following MRLs for milk) : The residue is fat-soluble and MRLs for milk and milk products are derived as explained in the introductions to Part 2 of the Guide to Codex Maximum Limits for Pesticide Residues and to Volume XIII of the Codex Alimentarius. (fat) (following MRLs for : The MRL applies to the fat of the meats) meat. Po : The (T)MRL accomodates post-harvest treatment of the commodity. PoP (following (T)MRLs for : The (T)MRL accomodates processed foods (Classes D post-harvest treatment of the and E in the Codex primary food commodity. Classification) T : The MRL is temporary, irrespective of the status of the ADI, until required information has been provided and evaluated. V (following (T)MRLs for : The (T)MRL accomodates veterinary commodities of animal origin) uses. If an MRL is an amendment, the previous value is also recorded, together with the year in which the level was estimated. The absence of a figure in the "Previous" column indicates that the recommendation is the first for the commodity or group concerned. The table includes the Codex Classification Numbers (CCNs) of both the compounds and the commodities listed, to facilitate reference to the Guide to Codex Maximum Limits for Pesticide Residues. CCNs for commodities are those of the revised Classification. Commodities are listed in the order of the "Types" in the Classification, and within each Type in alphabetical order. Different Types are not differentiated by sub-headings, but are separated from one another by spaces. The Types are listed in the following order: Type Code Fruits 01 Vegetables 02 Grasses 03 Nut and seeds 04 Herbs and spices 05 Mammalian products 06 Poultry products 07 Primary animal feed commodities of plant origin 11 Secondary food commodities of plant origin 12 Derived products of plant origin 13 ACCEPTABLE DAILY INTAKES (ADIs) AND MAXIMUM RESIDUE LIMITS (MRLs) Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) AMITRAZ 0.003 VO 0448 Tomato 0.5 - (122) 1980,1983,1984, 1985,1986 Residue: sum of amitraz and N-(2,4-dimethylphenyl)-N'-methylformamdine) calculated as N-(2,4-dimethylphenyl)-N'-methylformamidine Remarks: the residue definition is rephrased; the sense is unchanged ANILAZINE 0.1 VS 0624 Celery 10 - (163) VO 0448 Tomato 10 - GC 0640 Barley 0.2 - GC 0654 Wheat 0.1 - AS 0640 Barley straw and fodder, dry 10 - AS 0654 Wheat straw and fodder, dry 30 - Residue: anilazine Remarks: Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) BENDIOCARB 0.004 FP 0009 Pome fruits Withdrawn 0.02* (1982) (137) 1982,1984 VR 0574 Beetroot 0.05* - GC 0640 Barley Withdrawn 0.05* (1982) GC 0647 Oats Withdrawn 0.05* (1982) GC 0654 Wheat Withdrawn 0.05* (1982) AS 0640 Barley straw and fodder, dry Withdrawn 0.05* (1982) AS 0647 Oat straw and fodder, dry Withdrawn 0.05* (1982) AS 0654 Wheat straw and fodder, dry Withdrawn 0.05* (1982) BENDIOCARB Residue: Commodities of plant origin: (contd) unconjugated bendiocarb. Commodities of animal origin: sum of conjugated and unconjugated bendiocarb, 2,2-dimethyl-1,3-benzodioxol-4-ol and N-hydroxymethyl-bendiocarb, expressed as bendiocarb. Remarks: TMRLs for animal products are replaced by MRLs. Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) BITERTANOL 0.01 FP 0009 Pome fruits 2 1 (1988) (144) 1983,1984,1986, AL 1030 Bean forage 1987,1988 (green) 10 10 (1988) AL 1270 Peanut forage (dry wt) (green) 20 20 (1988) (dry wt) Residue: bitertanol Remarks: BROMIDE ION 1 (047) 1968,1969,1971, 1979,1981,1983, 1988 Residue: bromide ion Note: MRLs apply to bromide ion from all sources but do not include covalently bound bromine Remarks: The definition of the residue is unchanged, but attention is drawn to the explanatory note Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) CLOFENTEZINE 0.02 VC 0424 Cucumber 1 1 T (1986) (156) 1986,1987 Residue: clofentezine Remarks: CYFLUTHRIN 0.02 FP 0226 Apple 0.2 T - (157) 1986,1987 VO 0445 Peppers, Sweet 0.2 T - VO 0448 Tomato 0.05 T - GC 0645 Maize 0.05 T - SO 0691 Cotton seed 0.05 T - SO 0495 Rape seed 0.05 T - ML 0812 Cattle milk 0.1 F T - AF 0645 Maize forage 0.5 T - Residue: cyfluthrin Remarks: Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) DAMINOZIDE 0.5** FP 0226 Apple 5 30 (GL, 1977) (104) 1977,1983 FP 0230 Pear 5 30 (GL, 1977) All other commodities Withdrawn **Applies to daminozide containing less than 30 mg UDMH/kg Residue: daminozide Remarks: as an ADI has been estimated, the limits are MRLs. All previous GLs were recorded in 1977 DEMETON-S-METHYL 0.0003** (073) **Group ADI, applying to the sum of demeton-S-methyl, demeton-S-methylsulphon and 1973,1979,1982, oxydemeton-methyl 1984 Residue: sum of demeton-S-methyl, its sulphoxide and sulphone, expressed as demeton-S-methyl Remarks: as an ADI has been estimated, previously recorded GLs are converted to TMRLs. They are temporary until information on current use patterns and resulting residues has been provided. Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) DEMETON-S-METHYLSULPHON 0.0003** (164) **Group ADI, applying to the sum of demeton-S-methyl, demeton-S-methylsulphon and oxydemeton-methyl Residue: sum of demeton-S-methyl, its sulphoxide and sulphone, expressed as demeton-S-methyl Remarks: DINOCAP 0.001 (087) 1969,1974 Residue: dinocap and related nitro-octylphenols, expressed as dinocap Remarks: as an ADI has been estimated, previously recorded GLs are converted to TMRLs. They are temporary until information on current use patterns has been provided Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) ENDOSULFAN 0.006 FP 0009 Pome fruit 1 ) 2 for Fruit (032) (1989) FS 0013 Cherries 1 ) (1968) 1965,1967,1968, FS 0014 Plums ) 1971,1974,1975, (including Prunes) 1 ) 1982,1985 VB 0400 Broccoli 0.5 ) 2 for Vegetables VB 0404 Cauliflower 0.5 ) except Bulb VB 0041 Cabbages, Head ) onions, Carrots, except Cabbage, ) Potatoes, and Savoy 1 ) Sweet potatoes VB 0403 Cabbage, Savoy 2 ) (1974) VS 0624 Celery 2 ) VL 0464 Chard 2 ) VL 0469 Chicory leaves 1 ) VP 0526 Common bean 0.5 ) VL 0476 Endive 1 ) VP 0528 Garden pea) ) (young pods) 0.5 ) VL 0480 Kale 1 ) VL 0482 Lettuce, Head 1 ) VL 0483 Lettuce, Leaf 1 ) VL 0502 Spinach 2 ) VR 0596 Sugar beet 0.1 ) Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) ENDOSULFAN AL 1021 Alfalfa forage (contd) (green) 1 - AL 1023 Clover 1 - AL 1028 Trefoil 1 - AV 0596 Sugar beet leaves or tops 1 - Residue: sum of alpha- and beta-endosulfan and endosulfan sulphate Remarks: TADI replaced by ADI at slightly lower level. Previously estimated TMRLs that have not been amended are replaced by MRLs, except those for meat and milks which remain temporary until required information is provided ETHION 0.006 (034) (1990) 1968,1969,1970, 1972,1975,1982, 1983,1985,1986 Residue: ethion Remarks: TADI extended at same level for 1 year Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) FENITROTHION 0.005 CF 1211 Wheat flour 2 PoP 3 PoP (1979) (037) 1969,1974,1976, 1977,1979,1982, Residue: fenitrothion 1983,1984,1986, 1987,1988 Remarks: FLUSILAZOLE 0.001 FI 0327 Banana 0.1 - (165) FB 0269 Grapes 0.5 - FP 0009 Pome fruits 0.2 - VR 0596 Sugar beet 0.01* - GC 0640 Barley 0.1 1/ - GC 0650 Rye 0.1 1/ - GC 0654 Wheat 0.1 1/ - FLUSILAZOLE SO 0495 Rape seed 0.05 - (contd) MM 0812 Cattle meat 0.01* 1/ - MO 0812 Cattle, Edible offal of 0.02* 1/ - MF 0812 Cattle fat 0.01* 1/ - ML 0812 Cattle milk 0.01* 1/ - Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) PM 0840 Chicken meat 0.01* - PO 0840 Chicken, Edible offal of 0.01* - PE 0840 Chicken eggs 0.01* - AS 0640 Barley straw and fodder, dry 2 1/ - AS 0650 Rye straw and fodder, dry 2 1/ - AS 0654 Wheat straw and fodder, dry 2 1/ - DF 0269 Dried grapes 3 - Residue: flusilazole Remarks: 1/temporary pending receipt of required information Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) IMAZALIL 0.01 VR 0589 Potato 5 Po 5 Po T (110) (washed before (washed before analysis) analysis) 1977,1980,1984, (1988) 1985,1986,1988 Residue: imazalil Remarks: limit of 5 mg/kg was estimated by 1984 JMPR, temporary only because ADI was temporary. Became full MRL in 1986. Converted to TMRL by 1988 JMPR LINDANE 0.008 (048) 1965,1966,1967, 1968,1969,1970, (publ.with 1971 Residue: gamma-HCH evalns.),1973, 1974,1975,1977, Remarks: revised ADI at slightly lower level 1978,1979 Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) METALAXYL 0.03 VR 0577 Carrot 0.05* 0.1 (1987) (138) VA 0385 Onion, Bulb 2 0.1 (1987) 1982,1984,1985, 1986,1987 Residue: metalaxyl Remarks: METHOMYL 0.03 VS 0624 Celery 2 0.2 (1988) (094) VO 0448 Tomato 0.5 0.2 (1988) 1975,1976,1977, 1978,1986,1987, 1988 Residue: sum of methomyl and methyl hydroxythioacetimidate ("methomyl oxime"), expressed as methomyl Remarks: TADI replaced by ADI at higher level. TMRLs replaced by MRLs. METHOPRENE 0.1 SO 0697 Peanut 2 2 T (1984) (147) 1984,1986,1987, 1988 MO 0105 Edible offal (mammalian) 0.1 0.1 T (1984) Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) MM 0095 Meat 0.2 F 0.2 F T (1984) PE 0112 Eggs 0.05 0.05 T (1984) Residue: methoprene Remarks: OXYDEMETONMETHYL 0.0003** (166) 1965 (as demeton-S-methyl **Group ADI, applying to the sum of demeton-S-methyl, demeton-S-methylsulphon sulphoxide), and oxydemeton-methyl 1967, 1968 Residue: Remarks: PACLOBUTRAZOL 0.1 FP 0226 Apple 0.5 0.2 (1988) (161) 1988 Residue: paclobutrazol Remarks: Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) 2-PHENYLPHENOL 0.02 (056) (1990) 1969,1975,1983, 1985 Residue: sum of 2-phenylphenol and 2-phenylphenate, expressed as 2-phenylphenol Remarks: TADI extended at same level for 1 year PROCYMIDONE 0.1 FB 0272 Raspberries, (136) Red, Black 10 5 (GL) 1981,1982 Residue: procymidone Remarks: as an ADI has been estimated, previously recorded GLs are converted to MRLs TECNAZENE 0.01 VR 0589 Potato 10 Po 1 Po (1978) (115) (washed before (washed before 1974,1978,1981, analysis) analysis) 1983,1987 Residue: tecnazene Remarks: 1978 recommendation was temporary because the ADI was temporary Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) TERBUFOS 0.0002 FI 0327 Banana 0.05 - (167) VB 0400 Broccoli 0.05* - VB 0041 Cabbages, Head 0.05* - VB 0404 Cauliflower 0.1 VA 0385 Onion, Bulb 0.05* - VR 0589 Potato 0.5 T - VD 0541 Soya bean (dry) 0.05* - VR 0596 Sugar beet 0.1 - VO 0447 Sweet corn (corn-on-the-cob) 0.05 - VO 1275 Sweet corn (kernels) 0.05 - GC 0640 Barley 0.005* - GC 0645 Maize 0.05* - GC 0656 Popcorn 0.05* - GC 0654 Wheat 0.005* - SB 0716 Coffee beans 0.05* - SO 0691 Cotton seed 0.05* - SO 0485 Mustard seed 0.05* - SO 0697 Peanut 0.05* - SO 0495 Rape seed 0.05* - Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) TERBUFOS MM 0812 Cattle meat 0.05* - (contd) MO 0812 Cattle, Edible offal of 0.05* - ML 0812 Cattle milk 0.01* - PM 0840 Chicken meat 0.05* - PO 0840 Chicken, Edible offal of 0.05* - PE 0112 Eggs 0.01* - AV 1051 Fodder beet leaves or tops 1 - AF 0645 Maize forage 1 - AL 0697 Peanut fodder 1 - AL 1270 Peanut forage (green) 1 - AS 0081 Straw and fodder (dry) of cereal grains 1 - OC 0495 Rape seed oil, crude 0.05* - Residue: sum of terbufos, its oxygen analogue and their sulphoxides and sulphones, expressed as terbufos Remarks: Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) TRIADIMEFON 0.03 FB 0272 Raspberries, Red, (133) Black 2 0.2 (1981) 1979,1981,1983, 1984,1985,1986, GC 0640 Barley 1 0.5 (1984) 1987,1988 Residue: sum of triadimefon and triadimenol Remarks: TRIADIMENOL 0.05 FP 0226 Apple 0.2 - (168) FB 0269 Grapes 2 - VC 0424 Cucumber 0.1 - GC 0640 Barley 0.1 - GC 0650 Rye 0.1 - GC 0654 Wheat 0.1 - SB 0716 Coffee beans 0.1* - MM 0812 Cattle meat 0.05* - ML 0812 Cattle milk 0.01* - PM 0110 Poultry meat 0.05* - PE 0112 Eggs 0.05* - Pesticide Rec. Commodity Recommended MRL or ERL (CCN) max. CCN Name (mg/kg) Year(s) of ADI previous (mg/kg New Previous evaluation(s) bw) AS 0640 Barley straw and fodder, dry 5 - AS 0650 Rye straw and fodder, dry 5 - AS 0654 Wheat straw and fodder, dry 5 - Residue: triadimenol Remarks: VINCLOZOLIN 0.07 VO 0445 Peppers, Sweet 3 2 (1986) (159) 1986,1987,1988 SO 0495 Rape seed 1 - DH 1100 Hops, dry 40 - Residue: sum of vinclozolin and all metabolites containing the 3,5-dichloroaniline moiety, expressed as vinclozolin Remarks:
See Also: Toxicological Abbreviations