|CAS #: 786-19-6||S-4-Chlorophenylthiomethyl O,O-diethyl phosphorodithioate
Phosphorodithioic acid, S-(((4-chlorophenyl)thio)methyl) O,O-diethyl ester
| UN #: 3018
| EINECS #: 212-324-1
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion if formulations contain flammable/explosive solvents.||NO open flames.||Use water spray, foam, powder, carbon dioxide.|
|PREVENT GENERATION OF MISTS! STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR!|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Pupillary constriction, muscle cramp, excessive salivation. Sweating. Nausea. Headache. Dizziness. Laboured breathing. Convulsions. Unconsciousness.||Use ventilation (not if powder), local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Muscle twitching. Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain. Blurred vision.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Muscle twitching. Abdominal cramps. Vomiting. Diarrhoea. Further see Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT wash away into sewer. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in a well-ventilated room.|
|Do not transport with food and feedstuffs.
Severe marine pollutant.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C11H16ClO2PS3 / (CH3CH2)2P(S)SCH2SC6H4Cl
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
|The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to bees and birds. The substance may cause long-term effects in the aquatic environment. Avoid release to the environment in circumstances different to normal use.|
|Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
If the substance is formulated with solvents also consult the ICSCs of these materials.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
Symbol: T, N; R: 24/25-50/53; S: (1/2)-28-36/37-45-60-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations Carbophenothion (WHO Pesticide Residues Series 2) Carbophenothion (Pesticide residues in food: 1976 evaluations) Carbophenothion (Pesticide residues in food: 1977 evaluations) Carbophenothion (Pesticide residues in food: 1979 evaluations) Carbophenothion (Pesticide residues in food: 1980 evaluations) Carbophenothion (Pesticide residues in food: 1983 evaluations)