|CARBARYL||ICSC: 0121 (April 2004)|
Methyl carbamic acid 1-naphthyl ester
| CAS #: 63-25-2
| UN #: 2757
|EC Number: 200-555-0
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Liquid formulations containing organic solvents may be flammable.||NO open flames.||Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|PREVENT DISPERSION OF DUST! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Nausea. Vomiting. Pupillary constriction, muscle cramp, excessive salivation.||Use local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||Redness. Pain. See Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap.|
|Eyes||Redness. Pain.||Wear safety goggles or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal cramps. Diarrhoea. Nausea. Vomiting. Pupillary constriction. Muscle cramps. Excessive salivation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Give a slurry of activated charcoal in water to drink. Give one or two glasses of water to drink. Refer for medical attention . See Notes.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Remove all ignition sources. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Separated from oxidants and food and feedstuffs. Well closed. Keep in a well-ventilated room.|
|Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.5 mg/m3, as TWA; (skin); A4 (not classifiable as a human carcinogen); BEI issued.
MAK: (inhalable fraction): 5 mg/m3; peak limitation category: II(4); skin absorption (H)
|The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to birds and bees. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.|
|Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Symbol: Xn, N; R: 22-40-50; S: (2)-22-24-36/37-46-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations Carbaryl (EHC 153, 1994) Carbaryl (HSG 78, 1993) Carbaryl (PIM 147) Carbaryl (FAO Meeting Report PL/1965/10/1) Carbaryl (FAO/PL:CP/15) Carbaryl (FAO/PL:1967/M/11/1) Carbaryl (FAO/PL:1968/M/9/1) Carbaryl (FAO/PL:1969/M/17/1) Carbaryl (AGP:1970/M/12/1) Carbaryl (WHO Pesticide Residues Series 3) Carbaryl (WHO Pesticide Residues Series 5) Carbaryl (Pesticide residues in food: 1976 evaluations) Carbaryl (Pesticide residues in food: 1977 evaluations) Carbaryl (Pesticide residues in food: 1979 evaluations) Carbaryl (Pesticide residues in food: 1984 evaluations) Carbaryl (Pesticide residues in food: 1996 evaluations Part II Toxicological) Carbaryl (JMPR Evaluations 2001 Part II Toxicological) Carbaryl (IARC Summary & Evaluation, Volume 12, 1976)